703559

Lanthanum(III) chloride bis(lithium chloride) complex solution

0.6 M in THF

• Synonym(s): Lanthanum trichloride lithium chloride complex
• Linear Formula: LaCl₃ · 2LiCl
• CAS Number: 405204-22-0
• Molecular Weight: 330.05
• PubChem Substance ID: 329762049
• NACRES: NA.22

Properties

• form: liquid
• Quality Level: 100
• reaction suitability: reagent type: catalyst; core: lanthanum
• concentration: 0.6 M in THF; 16 % (w/w)
• density: 1.05 g/mL at 25 °C
• SMILES string: [Li]Cl.[Li]Cl.Cl[La](Cl)Cl
• InChI: 1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5
• InChI key: YSKOYVQYUJUXCN-UHFFFAOYSA-I

Description

Application

Selective 1,2-Additions with LaCl3•2LiCl

• Mediates Grignard additions
• Reagent for metal exchange reactions
• Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines

Legal Information

Product of Albemarle US Inc

Safety Information

• Pictograms: GHS02,GHS05,GHS07,GHS08
• Signal Word: Danger
• Hazard Statements: H225 - H290 - H302 - H317 - H318 - H335 - H336 - H351 - H412
• Precautionary Statements: P210 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1
• Supplementary Hazards: EUH019
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): 62.6 °F
• Flash Point(C): 17 °C
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves