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Sigma-Aldrich

4-Chlorophenylmagnesium bromide solution

greener alternative

1.0 M in 2-methyltetrahydrofuran

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Synonym(s):
(4-Chlorophenyl)magnesium bromide, p-Chlorophenylmagnesium bromide
Linear Formula:
ClC6H4MgBr
CAS Number:
Molecular Weight:
215.76
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

solution

Quality Level

reaction suitability

reaction type: Grignard Reaction

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Inherently Safer Chemistry for Accident Prevention
Learn more about the Principles of Green Chemistry.

concentration

1.0 M in 2-methyltetrahydrofuran

density

1.005 g/mL at 25 °C

greener alternative category

storage temp.

2-8°C

SMILES string

Clc1ccc([Mg]Br)cc1

InChI

1S/C6H4Cl.BrH.Mg/c7-6-4-2-1-3-5-6;;/h2-5H;1H;/q;;+1/p-1

InChI key

CDEMHJCJMMOFMB-UHFFFAOYSA-M

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This Item
262188772844772836
concentration

1.0 M in 2-methyltetrahydrofuran

concentration

1.0 M in diethyl ether

concentration

1.0 M in 2-methyltetrahydrofuran

concentration

1.0 M in 2-methyltetrahydrofuran

density

1.005 g/mL at 25 °C

density

0.887 g/mL at 25 °C

density

1.022 g/mL at 25 °C

density

0.970 g/mL

storage temp.

2-8°C

storage temp.

-

storage temp.

2-8°C

storage temp.

2-8°C

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

form

solution

form

liquid

form

solution

form

solution

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention. Find details here.

Application

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Packaging

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

8.6 °F - closed cup

Flash Point(C)

-13.0 °C - closed cup


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