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Merck

Hydrophilic Polymers

Blue hydrophilic polymer gel with bubbles

Hydrophilic polymers are designed to absorb, retain, or interact readily with water. Featuring polar functional groups such as hydroxyl, carboxyl, or amine moieties, these polymers—including polyvinyl alcohol (PVA), polyethylene glycol (PEG), and polyacrylamide—are highly versatile in aqueous environments. Their affinity for water makes them essential in biomedical fields (e.g., hydrogels for drug delivery and tissue engineering), personal care (e.g., absorbent hygiene products), and analytical chemistry (e.g., chromatography media and membranes). Their water-attracting nature supports processes where hydration, diffusion, or biological compatibility is critical.

Breakthroughs feel closer than ever with our comprehensive portfolio of hydrophilic polymers, classified according to chemical class and monomer functionality.


Products

solid (32)

powder (27)

viscous liquid (10)

liquid (8)

crystals (6)

powder or crystals (5)

0 - 100 (3)

101 - 200 (2)

201 - 300 (9)

401 - 500 (2)

CHNO containing functional groups (4)

CHO containing functional groups (1)

aliphatic functional groups (1)
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Showing 1-20 of 121
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Poly(vinyl alcohol)
341584

Poly(vinyl alcohol)

Mw 89,000-98,000, 99+% hydrolyzed

Polyethylenimine, branched
408727

Polyethylenimine, branched

average Mw ~25,000 by LS, average Mn ~10,000 by GPC, branched

Poly(acrylic acid)
181285

Poly(acrylic acid)

average Mv ~450,000

Poly(vinyl alcohol)
360627

Poly(vinyl alcohol)

Mw 8,000-10,000, 80% hydrolyzed

Polyethylenimine, branched
408719

Polyethylenimine, branched

average Mw ~800 by LS, average Mn ~600 by GPC

Poly(vinyl alcohol)
363065

Poly(vinyl alcohol)

Mw 150,000 (average), 99+% hydrolyzed

Poly(ethyleneimine) solution
408700

Poly(ethyleneimine) solution

average Mw 1800, 50 wt. % in H2O

Poly(ethyleneimine) solution
181978

Poly(ethyleneimine) solution

average Mn ~60,000 by GPC, average Mw ~750,000 by LS, 50 wt. % in H2O

Poly(vinyl alcohol)
363170

Poly(vinyl alcohol)

Mw 13,000-23,000, 87-89% hydrolyzed

Poly(vinyl alcohol)
363146

Poly(vinyl alcohol)

Mw 85,000-124,000, 99+% hydrolyzed

Poly(sodium 4-styrenesulfonate)
243051

Poly(sodium 4-styrenesulfonate)

average Mw ~70,000

Poly(acrylic acid)
323667

Poly(acrylic acid)

brittle and colorless in nature, Tg 106°C

Poly(diallyldimethylammonium chloride) solution
409022

Poly(diallyldimethylammonium chloride) solution

average Mw 200,000-350,000 (medium molecular weight), 20 wt. % in H2O

Poly(4-styrenesulfonic acid) solution
561223

Poly(4-styrenesulfonic acid) solution

Mw ~75,000, 18 wt. % in H2O

Poly(vinyl alcohol)
363138

Poly(vinyl alcohol)

Mw 31,000-50,000, 98-99% hydrolyzed

Mowiol<SUP>®</SUP> 4-88
81381

Mowiol® 4-88

Mw ~31,000

Sodium Polyacrylate
432784

Sodium Polyacrylate

cross-linked

Poly(<I>N</I>-isopropylacrylamide)
535311

Poly(N-isopropylacrylamide)

Mn ~40,000

Poly(acrylic acid) solution
416002

Poly(acrylic acid) solution

average Mw ~250,000, 35 wt. % in H2O

Poly(acrylic acid sodium salt)
447013

Poly(acrylic acid sodium salt)

average Mw ~5,100 by GPC, powder

You have viewed 1-20 of 121 results

ACRYLIC POLYMERS

Acrylics include various acrylic, acrylonitrile, acrylamide, and maleic anhydride polymers. These homo- and co-polymers have rigid, flexible, hydrophilic, or hydrophobic properties. Most of these polymers are thermoplastics and can be readily converted into a desired shape by a thermal process. Hence, they are commonly used in polymer coatings, adhesives, and fibers.

ETHER POLYMERS

Ethers have ether functionality in the main chain. They tend to be flexible and provide impact resistance to bulk properties. Many polyethers have functional groups at their chain ends and are used to prepare higher molecular weight polymers. Thus, they could also be classified as macromonomers and are commonly used in the preparation of polyesters and polyurethanes. Poly(propylene glycol) polymers and oligomers (DOWANOL®) are included in this category.

FLUOROCARBON POLYMERS

Fluorocarbon polymers are unique materials in that the polymer is not "wet" by hydrophilic or hydrophobic materials. They have very low coefficients of friction and have outstanding chemical and thermal resistance properties. Copolymers can be melt-processed more readily than poly(tetra-fluoroethylene).

POLYSTYRENE POLYMERS

Polystyrene and its copolymers have found important applications as films, foams, and structural components. Copolymers with diene monomers are cross-linked to improve physical properties and generate thermoplastic elastomers. Polystyrene film is highly transparent to visible radiation and has a high refractive index.

POLY(VINYL CHLORIDE)(PVC) POLYMERS

Poly(vinyl chloride) (PVC) is often highly plasticized to improve rheology for melt processing. It is highly susceptible to UV and high-temperature degradation and stabilizers are commonly added.

POLY(N-VINYLPYRROLIDONE)(PVP) POLYMERS

Poly(N-vinylpyrrolidone) (PVP) is a polar polymer with excellent film-forming and adhesion properties. It is commonly used in formulating hair sprays and hand creams as well as in the textile industry due to its affinity for many dyestuffs. PVP is a biocompatible polymer that has been used as a blood plasma substitute, although this application is becoming uncommon.


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