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For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
179825
Borane dimethyl sulfide complex
Sinónimos:
(Dimethyl sulfide)trihydroboron, BMS, Borane-dimethyl sulfide
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form
liquid
Quality Level
reaction suitability
reagent type: reductant
density
0.801 g/mL at 25 °C (lit.)
functional group
thioether
storage temp.
2-8°C
SMILES string
B.CSC
InChI
1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
Inchi Key
RMHDLBZYPISZOI-UHFFFAOYSA-N
Categorías relacionadas
1 of 4
Este artículo | 192120 | 255106 | 262064 |
|---|---|---|---|
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant |
| density 0.801 g/mL at 25 °C (lit.) | density 0.855 g/mL at 25 °C | density - | density 1.347 g/mL at 25 °C |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| form liquid | form liquid | form solid | form liquid |
| functional group thioether | functional group thioether | functional group thioether | functional group thioether |
General description
Application
- For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.[3]
- For the conversion of ozonides to alcohols.[4]
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.[5]
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.[6]
- For the hydroboration reduction and other applications.[7][8]
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.[9]
Packaging
Other Notes
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Water-react 1
Clase de almacenamiento
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 1
flash_point_f
64.4 °F
flash_point_c
18 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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