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Merck

206229

Ruthenium(III) chloride hydrate

ReagentPlus®

Sinónimos:

Ruthenium trichloride

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1 G

MXP 1,874.00

5 G

MXP 5,769.00

25 G

MXP 22,176.00

MXP 1,874.00


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Fórmula lineal:
RuCl3 · xH2O
Número CAS:
Peso molecular:
207.43 (anhydrous basis)
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
233-167-5
MDL number:
Form:
powder and chunks

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InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

SMILES string

O.Cl[Ru](Cl)Cl

product line

ReagentPlus®

form

powder and chunks

composition

Degree of hydration, ≤1 , Ruthenium content, 40.00-49.00%

reaction suitability

core: ruthenium, reagent type: catalyst

impurities

≤0.1% Insoluble matter (C=1%, 25% HCl)

Quality Level

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Este artículo
93157846377984050
form

powder and chunks

form

powder

form

powder and chunks

form

powder

Quality Level

200

Quality Level

100

Quality Level

100

Quality Level

100

impurities

≤0.1% Insoluble matter (C=1%, 25% HCl)

impurities

≤1000.0 ppm (trace metals analysis)

impurities

≤250.0 ppm Trace Metal Analysis

impurities

-

product line

ReagentPlus®

product line

-

product line

-

product line

-

composition

Degree of hydration, ≤1

composition

-

composition

-

composition

-

reaction suitability

reagent type: catalyst
core: ruthenium

reaction suitability

-

reaction suitability

reagent type: catalyst
core: ruthenium

reaction suitability

-

General description

ReagentPlus® ruthenium(III) chloride hydrate is a versatile and valuable compound in various scientific and industrial applications, particularly due to its catalytic properties and role in material science. Its ability to participate in numerous chemical reactions and processes makes it an essential reagent in both research and practical applications. It comes with black or grey color with insoluble matter ≤ 0.1 %; and % Ruthenium after reduction with Magnesium is 40.00 - 49.00 %.

Application

Ruthenium(III) chloride hydrate (RuCl·xHO) is a versatile compound with several applications across different fields. It can be used as a catalyst hydrogeneation, oxidation reachtions. For example, one of the study has found it as an efficient catalyst for the selective oxidation of fatty alcohols to aldehydes.[1] Due to its excellent conductivity and ability to withstand higher temperature, the product is used in electronics as a precursor for thin film deposition. Thin films of ruthenium and its derivatives are used in the fabrication of memory devices, microelectromechanical systems (MEMS) and integrated circuits. It can be used in the preparation of electrodes for electrochemical cells due to its good conductivity and stability. Ruthenium(III) chloride hydrate is used in the synthesis of ruthenium nanoparticles, which have applications in catalysis, electronics, and material science. Ruthenium compounds are being researched for their potential use as anticancer agents due to their ability to bind to DNA and inhibit cell proliferation.[2] In addition, ruthenium(III) chloride hydrate is utilized in the field of solar energy. It is used as a sensitizer in dye-sensitized solar cells (DSSCs). DSSCs are an alternative to traditional silicon-based photovoltaic cells with low cost and easy fabrication process. Ruthenium-based dyes absorb light and transfer electrons, initiating the energy conversion process in DSSCs. [3]

Features and Benefits

ReagentPlus® ruthenium(III) chloride hydrate has been designed and tested keeping the requirements of research applications with low insoluble matters, specifications ensuring the material is suitable for high-performance applications and provides consistency in experimental and industrial processes.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

Clase de almacenamiento

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificados de análisis (COA)

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TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Meser M Ali et al.
Journal of nanomedicine & nanotechnology, 10(6), 35248/2157-35248/7439 (2020-01-30)
Dye-sensitized solar cells (DSSCs) have attracted enormous attention in the last couple of decades due to their relatively small size, low cost and minimal environmental impact. DSSCs convert solar energy to electrical energy with the aid of a sensitizing dye.
Synthesis of ruthenium complexes and their catalytic applications: A review
Hafeez J, et al.
Arabian Journal of Chemistry, 15, 104165-104165 (2022)

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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