- 346152
346152
Ethynylmagnesium bromide solution
0.5 M in THF
Recommended Products
Quality Level
reaction suitability
reaction type: Grignard Reaction
concentration
0.5 M in THF
density
0.94 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
Br[Mg]C#C
InChI
1S/C2H.BrH.Mg/c1-2;;/h1H;1H;/q;;+1/p-1
InChI key
HUGJUYPSXULVQQ-UHFFFAOYSA-M
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This Item | 561754 | 364673 | 419591 |
|---|---|---|---|
| reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction | reaction suitability reaction type: Grignard Reaction |
| concentration 0.5 M in THF | concentration 0.5 M in THF | concentration 1.0 M in THF | concentration 0.5 M in THF |
| density 0.94 g/mL at 25 °C | density 0.950 g/mL at 25 °C | density 1.010 g/mL at 25 °C | density 0.937 g/mL at 25 °C |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| Quality Level 200 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
Application
- The preparation of the alkyne component in an enyne cross-metathesis leading to conjugated dienes.
- Ethynylation of chiral α-(dibenzylamino) aldehydes.
- The synthesis of ethynyl aziridines.
- To prepare alkyl(triethynyl)germanes from tert-alkyltrichlorogermanes and 2-butyltrichlorogermane.
- The preperation of a key intermediate in the total synthesis of (+)-4-demethoxydaunomycin.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 2
Supplementary Hazards
Storage Class Code
4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK
WGK 3
Flash Point(F)
-20.2 °F
Flash Point(C)
-29 °C
Personal Protective Equipment
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