429007

1-Propynylmagnesium bromide solution

0.5 M in THF

• Synonym(s): 1-Propyn-1-ylmagnesium bromide, Bromo(prop-1-yn-1-yl)magnesium, Bromo-1-propynylmagnesium
• Linear Formula: CH₃C≡CMgBr
• CAS Number: 16466-97-0
• Molecular Weight: 143.26
• Beilstein: 3929146
• Número MDL: MFCD00216588
• ID de la sustancia en PubChem: 24866829
• NACRES: NA.22

Properties

• Nivel de calidad: 200
• reaction suitability: reaction type: Grignard Reaction
• concentración: 0.5 M in THF
• bp: 65-67 °C
• densidad: 0.941 g/mL at 25 °C
• temp. de almacenamiento: 2-8°C
• SMILES string: CC#C[Mg]Br
• InChI: 1S/C3H3.BrH.Mg/c1-3-2;;/h1H3;1H;/q;;+1/p-1
• InChI key: YVJBCTFVENNIOV-UHFFFAOYSA-M

Description

Descripción general

1-Propynylmagnesiumbromide solution is 1-propynylmagnesium bromide in 0.5M tetrahydrofuran.1-propynylmagnesium bromide solution used as a Grignard reagent in chemical synthesis. This research reagent can be used for chemical and organic transformations. It is used as a regent in the conversion of [11C]CO2 to [11C] amides via Mitsunobu reaction.

Envase

100, 800 mL in Sure/Seal™

Aplicación

Preparation of hydroxy enynes which underwent gold(I)-catalyzed benzannulation leading to tetrahydronaphthalenes.

Safety Information

• pictogramas: GHS02,GHS05,GHS07,GHS08
• Palabra de señalización: Danger
• Frases de peligro: H225 - H261 - H302 - H314 - H335 - H351
• Consejos de prudencia: P201 - P210 - P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Clasificaciones de peligro: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 2
• Órganos de actuación: Respiratory system
• Riesgos supl.: EUH014 - EUH018 - EUH019
• Código de clase de almacenamiento: 4.3 - Hazardous materials, which set free flammable gases upon contact with water
• WGK: WGK 3
• Punto de inflamabilidad F: 30.2 °F - closed cup
• Punto de inflamabilidad C: -1 °C - closed cup
• Equipo de protección personal: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter