458139

Sigma-Aldrich

Luperox® TBH70X, tert-Butyl hydroperoxide solution

70 wt. % in H2O

Sinónimos:
tert-Butyl hydroperoxide solution, 1,1-Dimethylethyl hydroperoxide, TBHP, 2-Hydroperoxy-2-methylpropane
Fórmula lineal:
(CH3)3COOH
Número de CAS:
Peso molecular:
90.12
Beilstein/REAXYS Number:
1098280
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

12.25-14.20% active oxygen basis
69.0-80.0% (NH2OH, titration)

form

liquid

reaction suitability

reagent type: oxidant

concentration

70 wt. % in H2O

refractive index

n20/D 1.386

pH

4.3

bp

96.2 °C

density

0.93 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

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Application

Versatile reagent for oxidations.
Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Iron-Catalyzed Efficient Synthesis of Amides from Aldehydes and Amine Hydrochloride Salts

Packaging

1, 4 L in poly bottle
18 L in poly drum
25, 100 mL in poly bottle

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

signalword

Danger

hazcat

Acute Tox. 3 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C

storage_class_code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK Germany

WGK 3

Flash Point F

107.6 °F - closed cup

Flash Point C

42 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificado de Análisis

Certificado de origen

J. Chem. Res. Synop., 7, 390-394 (2003)
J. Catal., 224, 288-296 (2004)
Sci. Synth., 3, 91-131 (2004)
Laura Parma et al.
Cells, 9(2) (2020-02-07)
Unstable atherosclerotic plaques frequently show plaque angiogenesis which increases the chance of rupture and thrombus formation leading to infarctions. Hypoxia plays a role in angiogenesis and inflammation, two processes involved in the pathogenesis of atherosclerosis. We aim to study the...
Inorgorganica Chimica Acta, 357, 2237-2244 (2004)

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