Merck
Todas las fotos(1)

563110

Sigma-Aldrich

Diethyl azodicarboxylate solution

40 wt. % in toluene

Todas las fotos(1)
Sinónimos:
NSC 679015, Diethoxycarbonyldiazene solution, NSC 3474, DEAD, Unifoam AZ-AE 200, Diethyl azodiformate solution, 1,2-Ethoxycarbonyl diazene solution
Fórmula lineal:
C2H5OCON=NCOOC2H5
Número de CAS:
1972-28-7
Peso molecular:
174.15
Beilstein:
908662
Número MDL:
MFCD00009103
ID de la sustancia en PubChem:
24880080

concentración

40 wt. % in toluene

índice de refracción

n20/D 1.4690

bp

116-117 °C

densidad

0.956 g/mL at 25 °C

temp. de almacenamiento

2-8°C

SMILES string

CCOC(=O)\N=N/C(=O)OCC

InChI

1S/C6H10N2O4/c1-3-11-5(9)7-8-6(10)12-4-2/h3-4H2,1-2H3/b8-7+

InChI key

FAMRKDQNMBBFBR-BQYQJAHWSA-N

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Descripción general

DOT Special Approval Submission is Under Review. Availability is Estimated as March 2012.

Aplicación

Reactant for preparation of:
  • Immunostimulants α-Galactosylceramides
  • Cellotriose and cellotetraose analogues as transition state mimics for mechanistic studies of cellulases
  • Bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase
  • Derivatives of F200 and S383 with cannabinoid CB1 receptor binding activities
  • Aza-β-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes

Reagent for:
  • Annulation of N-protected imines
  • α-thiocyanation of enolizable ketones with ammonium thiocyanate
  • Diels-Alder reactions
A commonly used activating reagent in Mitsunobo reactions.

Envase

25, 100 g in glass bottle
100g unit contains ca. 40g DEAD solute
25g unit contains ca. 10g DEAD solute

Advertencia

Toxic, Irritant, Flammable

Palabra de señalización

Danger

Clasificaciones de peligro

Aquatic Chronic 3 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 2 - Self-react. C - Skin Irrit. 2 - STOT RE 2

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

4.1A - Other explosive hazardous materials

WGK

WGK 3

Punto de inflamabilidad F

105.8 °F - closed cup

Punto de inflamabilidad C

41 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificado de Análisis

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Certificado de origen

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Más documentos

FT-IR Condensed Phase
FT-NMR Spectra
Pressure-Temperature Nomograph
Spectra for FT-IR Raman
Structure Search

Quotes and Ordering

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