62420

Sigma-Aldrich

Lithium aluminum hydride

≥97.0% (gas-volumetric)

Sinónimos:
Lithium tetrahydroaluminate, LAH, Lithium alanate
Fórmula lineal:
LiAlH4
Número de CAS:
Peso molecular:
37.95
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

≥97.0% (gas-volumetric)

reaction suitability

reagent type: reductant

mp

125 °C (dec.) (lit.)

SMILES string

[Li].[AlH3]

InChI

1S/Al.Li.4H/q-1;+1;;;;

InChI key

OCZDCIYGECBNKL-UHFFFAOYSA-N

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Categorías relacionadas

General description

Lithium aluminum hydride (LiAlH4) is a powerful reducing agent used in organic synthesis to reduce esters, carboxylic acids, acyl chlorides, aldehydes, epoxides, and ketones into the corresponding alcohols. It also converts amide, nitro, nitrile, imine, oxime, and azide compounds into amines.

Application

Reactant involved in:
  • Dehydrogenation studied with various catalysts
  • Regeneration of methoxysilanes via reduction
  • Transition metal electrophilic hydrogen activation via heterolytic cleavage
  • Formation of nickel hydrogenation catalysts
  • Hydrogen sorption
  • Electrodeposition of Al on W-Cu substrates

Packaging

packed in plastic bag, which is soluble at 45-60°C in hydrocarbons, THF and dioxane

pictograms

FlameCorrosion

signalword

Danger

hazcat

Eye Dam. 1 - Skin Corr. 1A - Water-react. 1

storage_class_code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK Germany

WGK 1

Flash Point F

Not applicable

Flash Point C

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificado de Análisis

Certificado de origen

W. Han, et al.,
International Journal of Hydrogen Energy, 36, 12305-12312 (2011)
L. B. Belykh, et al.,
Applied Catalysis, 401, 65-72 (2011)
J. W. Runyon, et al.,
Australian Journal of Chemistry, 64, 1165-1172 (2011)
Rafi-ud-din, et al.,
The Journal of Physical Chemistry C, 115, 13088-13099 (2011)
Q. Chen, et al.,
Surface and Coating Tech., 205, 4418-4424 (2011)

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