20256

Sigma-Aldrich

tert-Butyl methyl ether

puriss. p.a., ≥99.5% (GC)

Sinónimos:
MTBE, Methyl tert-butyl ether
Fórmula lineal:
(CH3)3COCH3
Número de CAS:
Peso molecular:
88.15
Beilstein/REAXYS Number:
1730942
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.07

Quality Level

vapor density

3.1 (vs air)

vapor pressure

4.05 psi

grade

puriss. p.a.

assay

≥99.5% (GC)

form

liquid

autoignition temp.

705 °F

expl. lim.

15.1 %

impurities

≤0.0005% peroxides (as H2O2)
≤0.005% free acid (as CH3COOH)
≤0.05% water

evapn. residue

≤0.005%

refractive index

n20/D 1.362-1.376
n20/D 1.369 (lit.)

bp

55-56 °C (lit.)

mp

-110 °C

density

0.736-0.744 g/mL at 20 °C
0.74 g/mL at 25 °C (lit.)

cation traces

Al: ≤0.5 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

SMILES string

COC(C)(C)C

InChI

1S/C5H12O/c1-5(2,3)6-4/h1-4H3

InChI key

BZLVMXJERCGZMT-UHFFFAOYSA-N

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Categorías relacionadas

pictograms

FlameExclamation mark

signalword

Danger

hazcat

Flam. Liq. 2 - Skin Irrit. 2

storage_class_code

3 - Flammable liquids

WGK Germany

WGK 1

Flash Point F

-18.4 °F - closed cup

Flash Point C

-28 °C - closed cup

Certificado de Análisis

Certificado de origen

J R Hanson et al.
Applied and environmental microbiology, 65(11), 4788-4792 (1999-11-05)
A bacterial strain, PM1, which is able to utilize methyl tert-butyl ether (MTBE) as its sole carbon and energy source, was isolated from a mixed microbial consortium in a compost biofilter capable of degrading MTBE. Initial linear rates of MTBE...
Kun-Chang Huang et al.
Chemosphere, 49(4), 413-420 (2002-10-09)
The kinetics of heat-assisted persulfate oxidation of methyl tert-butyl ether (MTBE) in aqueous solutions at various pH, temperature, oxidant concentration and ionic strength levels was studied. The MTBE degradation was found to follow a pseudo-first-order decay model. The pseudo-first-order rate...
R J Steffan et al.
Applied and environmental microbiology, 63(11), 4216-4222 (1997-11-15)
Several propane-oxidizing bacteria were tested for their ability to degrade gasoline oxygenates, including methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and tert-amyl methyl ether (TAME). Both a laboratory strain and natural isolates were able to degrade each compound after...
Sarah K Abbott et al.
Lipids, 48(3), 307-318 (2013-01-29)
We have developed a protocol suitable for high-throughput lipidomic analysis of human brain samples. The traditional Folch extraction (using chloroform and glass-glass homogenization) was compared to a high-throughput method combining methyl-tert-butyl ether (MTBE) extraction with mechanical homogenization utilizing ceramic beads....
Mònica Rosell et al.
Environmental science & technology, 46(9), 4757-4766 (2012-03-30)
Although the uniform initial hydroxylation of methyl tert-butyl ether (MTBE) and other oxygenates during aerobic biodegradation has already been proven by molecular tools, variations in carbon and hydrogen enrichment factors (ε(C) and ε(H)) have still been associated with different reaction...

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