Merck
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32222

Sigma-Aldrich

Dichloromethane

puriss. p.a., ACS reagent, reag. ISO, ≥99.9% (GC)

Sinónimos:
Methylene chloride, methylene chloride
Empirical Formula (Hill Notation):
CH2Cl2
Número de CAS:
Peso molecular:
84.93
Beilstein:
1730800
Número de EC:
Número MDL:
ID de la sustancia en PubChem:
NACRES:
NA.04

Nivel de calidad

200

grado

ACS reagent
puriss. p.a.

Agency

reag. ISO

densidad de vapor

2.9 (vs air)

presión de vapor

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

ensayo

≥99.9% (GC)

formulario

liquid

temp. de autoignición

1223 °F

contiene

~25 mg/L amylene as stabilizer

lim. expl.

22 %

impurezas

≤0.00002% free chlorine (Cl)
≤0.0005% formaldehyde
≤0.001% free acid (as HCl)
≤0.001% non-volatile matter
≤0.01% chloroform (GC)
≤0.01% tetrachloromethane (GC)
≤0.01% water (Karl Fischer)
≤0.05% ethanol (GC)

índice de refracción

n20/D 1.4235-1.4245
n20/D 1.424 (lit.)

bp

39.8-40 °C (lit.)

mp

−97 °C (lit.)

densidad

1.320-1.330 g/L at 20 °C
1.325 g/mL at 25 °C (lit.)

trazas de anión

chloride (Cl-): ≤0.5 mg/kg

trazas de catión

Al: ≤0.5 mg/kg
B: ≤0.02 mg/kg
Ba: ≤0.1 mg/kg
Bi: ≤0.1 mg/kg
Ca: ≤0.5 mg/kg
Cd: ≤0.05 mg/kg
Co: ≤0.02 mg/kg
Cr: ≤0.02 mg/kg
Cu: ≤0.02 mg/kg
Fe: ≤0.1 mg/kg
K: ≤0.5 mg/kg
Li: ≤0.1 mg/kg
Mg: ≤0.1 mg/kg
Mn: ≤0.02 mg/kg
Mo: ≤0.1 mg/kg
Na: ≤0.5 mg/kg
Ni: ≤0.02 mg/kg
Pb: ≤0.1 mg/kg
Sn: ≤0.1 mg/kg
Sr: ≤0.1 mg/kg
Zn: ≤0.1 mg/kg

SMILES string

ClCCl

idoneidad

passes test for reaction against H2SO4

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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Descripción general

Dichloromethane has been tested as a solvent medium for dipyridine-chromium(VI) oxide. Solubility was reported to be 12.5g/100ml. The apparent adsorption constant of the TiO2 loaded activated carbon for dichloromethane was found to be inversely proportional to the quantity of loaded TiO2.

Aplicación

Dichloromethane may be used as a solvent for the preparation of stock solutions of carotenoids. It may be employed as a solvent in the synthesis of polylactide-based (PLA) thin films.

Otras notas

The article number 32222-4X2.5L will be discontinued. Please order the single bottle 32222-2.5L which is physically identical with the same exact specifications.
The article number 32222-4X2.5L-M will be discontinued. Please order the single bottle 32222-2.5L-M which is physically identical with the same exact specifications.
The article number 32222-6X1L will be discontinued. Please order the single bottle 32222-1L which is physically identical with the same exact specifications.
The article number 32222-6X1L-M will be discontinued. Please order the single bottle 32222-1L-M which is physically identical with the same exact specifications.

pictogramas

Exclamation markHealth hazard

Palabra de señalización

Warning

Frases de peligro

Clasificaciones de peligro

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Órganos de actuación

Central nervous system

Código de clase de almacenamiento

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Punto de inflamabilidad F

does not flash

Punto de inflamabilidad C

does not flash

Certificado de Análisis

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R Re et al.
Free radical biology & medicine, 26(9-10), 1231-1237 (1999-06-25)
A method for the screening of antioxidant activity is reported as a decolorization assay applicable to both lipophilic and hydrophilic antioxidants, including flavonoids, hydroxycinnamates, carotenoids, and plasma antioxidants. The pre-formed radical monocation of 2,2'-azinobis-(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS*+) is generated by oxidation
Dipyridine-chromium (VI) oxide oxidation of alcohols in dichloromethane.
Collins JC, et al.
Tetrahedron Letters, 9(30), 3363-3366 (1968)
V Melissinaki et al.
Biofabrication, 3(4), 045005-045005 (2011-09-21)
This study reports on the production of high-resolution 3D structures of polylactide-based materials via multi-photon polymerization and explores their use as neural tissue engineering scaffolds. To achieve this, a liquid polylactide resin was synthesized in house and rendered photocurable via
Effect of activated carbon content in TiO2-loaded activated carbon on photodegradation behaviors of dichloromethane.
Torimoto T, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 103(1), 153-157 (1997)
Angharad M Roberts et al.
Science translational medicine, 7(270), 270ra6-270ra6 (2015-01-16)
The recent discovery of heterozygous human mutations that truncate full-length titin (TTN, an abundant structural, sensory, and signaling filament in muscle) as a common cause of end-stage dilated cardiomyopathy (DCM) promises new prospects for improving heart failure management. However, realization

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