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Metathesis

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facet applications:Metathesis
facet content type:Technical Article
Metathesis
Olefin metathesis is now a well-entrenched synthetic technique, and is a powerful method for the clean construction of innumerable classes of chemical architectures.
Rh2(esp)2 Catalyst
New! Rh2(esp)2, and exceptionally efficient and selective catalyst for C-H amination.
N-Heterocyclic Carbene-Copper Complexes
N-Heterocyclic Carbene-Copper Complexes
N-Heterocyclic Carbene (NHC) Compounds
Rovis has demonstrated that triazolium salt in the presence of a base can act as an N-heterocyclic carbene organocatalyst1 in highly enantioselective intramolecular Stetter reactions.
Ring-Closing Alkyne Metathesis (RCAM)
Alkyne metathesis has been a useful tool for C–C bond formation since the discovery of structurally well-defined metal alkylidynes by Schrock and coworkers.
N-Heterocyclic Carbenes
NHC (N-heterocyclic carbenes) are ligands for rapid synthesis of novel organometallic complexes. NHC ligands have practical use when bound to metals.
Rieke® Highly Reactive Metals
Metal-enhanced organic synthesis via organometallic intermediates is a widely used preparative route for thousands of organic compounds.
N-Heterocyclic Carbene (NHC) Ligands
Metal complex-catalyzed cross-coupling reactions of unactivated substrates introduce diverse phosphine ligands in chemical marketplace.
CBILS©: Cell-Based Immunotherapy Logistics System
CBILS© offers a simple, elegant synthetic method for the production of ionic liquids, developed by the Austrian company proionic.
N-Heterocyclic Carbene (NHC) Ligands
Emerging class of privileged ligands
TPGS-750-M: Second-Generation Amphiphile for Organometallic Chemistry in Water at Room Temperature
Lipshutz and co-workers have recently developed a second generation technology to their original PTS-enabling surfactant based on the polyoxyethanyl-α-tocopheryl succinate derivative, TPGS-750-M.
Hydrosilylation Catalyst
Trost group's protocol yields α-vinylsilanes from terminal acetylenes using [Cp*Ru(MeCN)3]PF6 catalyst and others for hydrosilylation.