Merck
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673587

Sigma-Aldrich

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II)

Synonym(s):
Pd(II) meso-tetra(pentafluorophenyl)porphine
Empirical Formula (Hill Notation):
C44H8F20N4Pd
CAS Number:
Molecular Weight:
1078.95
MDL number:
PubChem Substance ID:
NACRES:
NA.23

form

solid

Quality Level

mp

>300 °C (dec.)

λmax

400 nm in acetone

storage temp.

−20°C

SMILES string

Fc1c(F)c(F)c(c(F)c1F)-c2c3ccc(n3)c(-c4c(F)c(F)c(F)c(F)c4F)c5ccc6c(-c7c(F)c(F)c(F)c(F)c7F)c8ccc(n8)c(-c9c(F)c(F)c(F)c(F)c9F)c%10ccc2n%10[Pd]n56

InChI

1S/C44H8F20N4.Pd/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;/h1-8H;/q-2;+2/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;

InChI key

GRRRJZUTYPIXFO-HQJDZOCDSA-N

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This Item
392014303038441813
form

solid

form

solid

form

-

form

solid

mp

>300 °C (dec.)

mp

-

mp

-

mp

>300 °C (lit.)

λmax

400 nm in acetone

λmax

393 nm

λmax

421 nm

λmax

466 nm

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

storage temp.

−20°C

storage temp.

-

storage temp.

-

storage temp.

-

General description

5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II) is a phosphorescent dye that is a derivative of palladium(II). It can be used as a singlet oxygen sensitizer due to the presence of fluorine atoms. It provides photostability and is resistant to oxidation.

Application

It can be used as a porphyrin dye with a high quantum yield for use in the fabrication of oxygen sensors.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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