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Merck

747793

Sigma-Aldrich

(Ir[dF(CF3)ppy]2(dtbpy))PF6

solid

Synonym(s):

[Ir{dF(CF3)ppy}2(dtbpy)]PF6, [4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]Iridium(III) hexafluorophosphate

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100 MG
RM 798.00
1 G
RM 5,273.00

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100 MG
RM 798.00
1 G
RM 5,273.00

About This Item

Empirical Formula (Hill Notation):
C42H34F16IrN4P
CAS Number:
Molecular Weight:
1121.91
MDL number:
UNSPSC Code:
12161600
NACRES:
NA.22

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RM 798.00


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Product Name

(Ir[dF(CF3)ppy]2(dtbpy))PF6,

form

solid

Quality Level

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

mp

>300 °C

photocatalyst activation

450 nm

SMILES string

F[P](F)(F)(F)(F)F.CC(C)(C)C1=CC=[N@H]2C(=C1)C3=CC(=CC=[N@@H]3[Ir]2456c7cc(F)cc(F)c7C8=CC=C(C=[N]48)C(F)(F)F)C(C)(C)C.Fc9cc(F)c(C%10=[N]5C=C(C=C%10)C(F)(F)F)c6c9

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1 of 4

This Item
901409908568905917
reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

-

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

form

solid

form

solid

form

powder or crystals

form

powder

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

-

mp

>300 °C

mp

-

mp

>300 °C

mp

-

photocatalyst activation

450 nm

photocatalyst activation

450 nm

photocatalyst activation

460 nm

photocatalyst activation

465 nm

Application

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.[1][2][3][4][5]It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.[3]

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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