Merck
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809330

Sigma-Aldrich

Fe/ppm Pd for nitro group reductions

MDL number:
NACRES:
NA.22

form

solid

Quality Level

composition

FeCl2 (372870), 23.3-27.4 wt. %
MgCl2 (M8266), 15.3-18.8 wt. %
Pd (203939), <0.3 wt. %
THF (186562), 53.5-61.6 wt. %

reaction suitability

core: iron
reagent type: catalyst

storage temp.

2-8°C

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form

solid

form

-

form

-

form

powder, crystals or chunks

reaction suitability

core: iron, reagent type: catalyst

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

reaction suitability

core: iron, reaction type: Cross Couplings, reagent type: catalyst

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

composition

FeCl2 (372870), 23.3-27.4 wt. %

composition

-

composition

-

composition

-

Application

When these nanoparticles (NPs) are used along with PEG-containing designer surfactants such as TPGS-750-M, a facile reduction of nitro compounds can be effected in water at room temperature. The transformation is highly chemoselective and tolerates a large variety of functional groups.

Caution

Handle under nitrogen and store under argon in refrigerator.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

1.4 °F

Flash Point(C)

-17 °C


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