791105

Zinc chloromethanesulfinate

95% (H-NMR)

• Synonym(s): Baran MCMS Reagent
• Empirical Formula (Hill Notation): C₂H₄Cl₂O₄S₂Zn
• CAS Number: 55066-41-6
• Molecular Weight: 292.48
• NACRES: NA.22
• PubChem Substance ID: 329768259
• UNSPSC Code: 12352101
• MDL number: MFCD27952553
• Assay: 95% (H-NMR)
• Form: solid

Properties

• Quality Level: 100
• assay: 95% (H-NMR)
• form: solid
• reaction suitability: reaction type: C-C Bond Formation, reagent type: catalyst; reaction type: C-H Activation, reagent type: diversification reagent
• mp: 190-195 °C
• functional group: chloro, sulfinic acid
• storage temp.: 2-8°C
• SMILES string: ClCS(O[Zn]OS(CCl)=O)=O
• InChI: 1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2
• InChI key: HEKATMPPXNXYJU-UHFFFAOYSA-L

Description

Application

Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319
• pcodes: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable