222380

Allylpalladium(II) chloride dimer

98%

• Synonym(s): [PdCl(C₃H₅)]₂
• Empirical Formula (Hill Notation): C₆H₁₀Cl₂Pd₂
• CAS Number: 12012-95-2
• Molecular Weight: 365.89
• Beilstein: 4124623
• EC Number: 234-579-8
• MDL number: MFCD00044874
• PubChem Substance ID: 24853328

Properties

• Quality Level: 200
• assay: 98%
• form: solid
• reaction suitability: core: palladium; reagent type: catalyst; reaction type: C-H Activation
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• greener alternative category: Aligned
• storage temp.: 2-8°C
• SMILES string: Cl[Pd]CC=C.Cl[Pd]CC=C
• InChI: 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2
• InChI key: TWKVUTXHANJYGH-UHFFFAOYSA-L

Description

General description

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Allylpalladium(II) chloride dimer has been employed for the following studies:

• Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
• Synthesis of N-heterocyclic carbene-palladium-η³-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
• Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
• As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

Packaging

100, 500 mg in glass bottle

1, 5 g in glass bottle

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315
• Precautionary Statements: P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
• Hazard Classifications: Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves