224758

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate

powder

• Synonym(s): Ru(BPY)₃, Ruthenium-tris(2,2′-bipyridyl) dichloride, Tris(2,2′-bipyridyl)ruthenium(II) chloride hexahydrate
• Empirical Formula (Hill Notation): C₃₀H₂₄Cl₂N₆Ru · 6H₂O
• CAS Number: 50525-27-4
• Molecular Weight: 748.62
• MDL number: MFCD00149670
• UNSPSC Code: 12352103
• PubChem Substance ID: 24853454
• NACRES: NA.23

Properties

• form: powder
• Quality Level: 100
• reaction suitability: core: ruthenium; reaction type: Photocatalysis; reagent type: catalyst
• mp: >300 °C (lit.)
• photocatalyst activation: 450 nm
• SMILES string: [H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6
• InChI: 1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2
• InChI key: WHELTKFSBJNBMQ-UHFFFAOYSA-L

Description

General description

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices.[1]

Application

• Used in the synthesis of hybrid catalysts which are used in oxidase based biosensors.[2]
• Used as a luminophore for multiplexed signalling in bio analysis.[3]
• Used in oxygen assesment in living cells.[4][5][6]

Learn More at the Professor and Product Portal of Professor Teshik Yoon and Professor Corey Stephenson.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves