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  • A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity.

A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity.

Journal of the American Chemical Society (2006-09-07)
Shengqian Ma, Hong-Cai Zhou
PMID16953594
ABSTRACT

A metal-organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2 and CH4 adsorption enthalpies of PCN-9 are among the highest reported thus far.