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Merck

105228

Sigma-Aldrich

1,1,1,3,3,3-Hexafluoro-2-propanol

≥99%

Synonym(s):

HFP, Hexafluoroisopropanol

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PLN 188.00
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PLN 522.00
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PLN 1,850.00
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PLN 6,920.00

PLN 188.00


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5 G
PLN 188.00
25 G
PLN 522.00
100 G
PLN 1,850.00
500 G
PLN 6,920.00

About This Item

Linear Formula:
(CF3)2CHOH
CAS Number:
Molecular Weight:
168.04
Beilstein:
1841007
EC Number:
MDL number:
UNSPSC Code:
12352104
PubChem Substance ID:
NACRES:
NA.22

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PLN 188.00


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Quality Level

Assay

≥99%

refractive index

n20/D 1.275 (lit.)

bp

59 °C (lit.)

mp

−4 °C (lit.)

density

1.596 g/mL at 25 °C (lit.)

functional group

fluoro
hydroxyl

SMILES string

OC(C(F)(F)F)C(F)(F)F

InChI

1S/C3H2F6O/c4-2(5,6)1(10)3(7,8)9/h1,10H

InChI key

BYEAHWXPCBROCE-UHFFFAOYSA-N

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1 of 4

This Item
525178.045151612594
assay

≥99%

assay

≥99.8% (GC)

assay

-

assay

-

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

-

mp

−4 °C (lit.)

mp

−4 °C (lit.)

mp

-3 °C

mp

−4 °C (lit.)

bp

59 °C (lit.)

bp

59 °C (lit.)

bp

58 °C/1013 hPa

bp

59 °C (lit.)

density

1.596 g/mL at 25 °C (lit.)

density

1.596 g/mL at 25 °C (lit.)

density

1.62 g/cm3 at 20 °C

density

1.596 g/mL at 25 °C (lit.)

refractive index

n20/D 1.275 (lit.)

refractive index

n20/D 1.275 (lit.)

refractive index

-

refractive index

n20/D 1.275 (lit.)

General description

1,1,1,3,3,3-Hexafluoro-2-propanol is a solution-phase peptide chemistry solvent.[1] This fluorinated polar solvent of high ionizing power facilitates Friedel–Crafts-type reactions, using covalent reagents in the absence of a Lewis acid catalyst.[2] It also enhances the efficiency of rhodium(I)-catalyzed [4+2] intramolecular cycloaddition of ether-tethered alkynyl dienes and [5+2] cycloaddition of alkynyl vinylcyclopropanes.[3] 1,1,1,3,3,3-Hexafluoro-2-propanol clusters catalyzes the epoxidation of cyclooctene and 1-octene with hydrogen peroxide.[4]

Application

1,1,1,3,3,3-Hexafluoro-2-propanol was used for preparing hexafluoroalcohol-functionalized methacrylate polymers for lithographic/nanopatterning materials[5].

Pictograms

Health hazardCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Repr. 2 - Skin Corr. 1A - STOT RE 2 Oral

Target Organs

Central nervous system

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 2

Flash Point(F)

No data available

Flash Point(C)

No data available

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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