Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
179825
Borane dimethyl sulfide complex
Synonym(s):
(Dimethyl sulfide)trihydroboron, BMS, Borane-dimethyl sulfide
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About This Item
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form
liquid
reaction suitability
reagent type: reductant
density
0.801 g/mL at 25 °C (lit.)
functional group
thioether
storage temp.
2-8°C
SMILES string
B.CSC
InChI
1S/C2H6S.BH3/c1-3-2;/h1-2H3;1H3
InChI key
RMHDLBZYPISZOI-UHFFFAOYSA-N
Related Categories
1 of 4
This Item | 192120 | 255106 | 262064 |
|---|---|---|---|
| reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant | reaction suitability reagent type: reductant |
| density 0.801 g/mL at 25 °C (lit.) | density 0.855 g/mL at 25 °C | density - | density 1.347 g/mL at 25 °C |
| Quality Level 200 | Quality Level 200 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. - | storage temp. - |
| form liquid | form liquid | form solid | form liquid |
| functional group thioether | functional group thioether | functional group thioether | functional group thioether |
General description
Application
- For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.[3]
- For the conversion of ozonides to alcohols.[4]
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.[5]
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.[6]
- For the hydroboration reduction and other applications.[7][8]
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.[9]
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Other Notes
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Water-react 1
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
64.4 °F
Flash Point(C)
18 °C
Personal Protective Equipment
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If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfHelpful?
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