L-Serine methyl ester hydrochloride

Name: <SC>L</SC>-Serine methyl ester hydrochloride
Brand: ALDRICH
Price: 200 PLN

98%, for peptide synthesis

Synonym(s):

L-Serine methyl ester·HCl

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About This Item

Linear Formula:

HOCH₂CH(NH₂)COOCH₃ · HCl

CAS Number:

5680-80-8

Molecular Weight:

155.58

Beilstein:

3559591

EC Number:

227-140-7

MDL number:

MFCD00063680

UNSPSC Code:

12352209

eCl@ss:

32160406

PubChem Substance ID:

24865794

NACRES:

NA.22

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Product Name

L-Serine methyl ester hydrochloride, 98%

Quality Level

100

Assay

98%

form

powder

optical activity

[α]20/D +3.4°, c = 4 in methanol

reaction suitability

reaction type: solution phase peptide synthesis

mp

163 °C (dec.) (lit.)

application(s)

peptide synthesis

SMILES string

Cl.COC(=O)[C@@H](N)CO

InChI

1S/C4H9NO3.ClH/c1-8-4(7)3(5)2-6;/h3,6H,2,5H2,1H3;1H/t3-;/m0./s1

InChI key

NDBQJIBNNUJNHA-DFWYDOINSA-N

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Related Categories

Amino Acids, Resins & Reagents for Peptide Synthesis

Chemistry & Biochemicals

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Show Differences

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This Item	860409	L1002	287067
Sigma-Aldrich 412201 L-Serine methyl ester hydrochloride	Sigma-Aldrich 860409 L-Methionine methyl ester hydrochloride	Sigma-Aldrich L1002 L-Leucine methyl ester hydrochloride	Sigma-Aldrich 287067 L-Proline methyl ester hydrochloride
form powder	form powder	form powder or crystals	form solid
assay 98%	assay 98%	assay 98%	assay 98%
optical activity [α]20/D +3.4°, c = 4 in methanol	optical activity [α]22/D +25.9°, c = 1 in H₂O	optical activity [α]22/D +13°, c = 2 in H₂O	optical activity [α]20/D −31°, c = 0.5 in H₂O
mp 163 °C (dec.) (lit.)	mp 151-153 °C (lit.)	mp 151-153 °C (lit.)	mp 69-71 °C (lit.)
Quality Level 100	Quality Level 200	Quality Level 100	Quality Level 100
reaction suitability reaction type: solution phase peptide synthesis	reaction suitability reaction type: solution phase peptide synthesis	reaction suitability reaction type: solution phase peptide synthesis	reaction suitability reaction type: solution phase peptide synthesis

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Systematic Detection of Amino Acid Substitutions in Proteomes Reveals Mechanistic Basis of Ribosome Errors and Selection for Translation Fidelity.

Ernest Mordret et al.

Molecular cell, 75(3), 427-441 (2019-07-30)

The translation machinery and the genes it decodes co-evolved to achieve production throughput and accuracy. Nonetheless, translation errors are frequent, and they affect physiology and protein evolution. Mapping translation errors in proteomes and understanding their causes is hindered by lack

The novel and efficient direct synthesis of N,O-acetal compounds using a hypervalent iodine(III) reagent: an improved synthetic method for a key intermediate of discorhabdins.

Yu Harayama et al.

Chemical communications (Cambridge, England), (13)(13), 1764-1766 (2005-03-26)

The use of hypervalent iodine(III) reagents allowed us to develop the novel and efficient direct synthesis of N,O-acetal compounds via the oxidative fragmentation reaction of alpha-amino acids or alpha-amino alcohols; furthermore, we succeeded in developing an improved synthesis of the

Theoretical evidence for pyramidalized bicyclic serine enolates in highly diastereoselective alkylations.

Carlos Aydillo et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 13(17), 4840-4848 (2007-03-17)

A new chiral serine equivalent and its enantiomer have been synthesized from (S)- and (R)-N-Boc-serine methyl esters (Boc: tert-butyloxycarbonyl). The use of these compounds as chiral building blocks has been demonstrated in the synthesis of alpha-alkyl alpha-amino acids by diastereoselective

Aziridinium from N,N-dibenzyl serine methyl ester: synthesis of enantiomerically pure beta-amino and alpha,beta-diamino esters.

Cédric Couturier et al.

Organic letters, 8(10), 2183-2186 (2006-05-05)

[reaction: see text] Reaction of N,N-dibenzyl-O-methylsulfonyl serine methyl ester with a variety of heteronucleophiles (sodium azide, sodium phthalimide, amines, thiols) and carbanions (sodium malonate) gave, via an aziridinium intermediate, the corresponding beta-amino or alpha,beta-diamino ester in good to excellent yield.

Contribution of the anomeric effect to the solution and crystal structure of [1S,2S,6S,7s]-1,6-diaza-4,9-dioxa-2,7-dimethoxycarbonylbicyclo[4.4.1]undecane, a condensation product of L-serine methyl ester with formaldehyde.

J Sélambarom et al.

Carbohydrate research, 330(1), 43-51 (2001-02-24)

The reaction of L-serine methyl ester hydrochloride (1) with paraformaldehyde (2) in dichloromethane in the presence of triethylamine afforded a novel compound: [lS,2S,6S,7S]-1,6-diaza-4,9-dioxa-2,7-dimethoxycarbonylbicyclo[4.4.1]undecane (4) as a 2:3 adduct of 1 with 2. 1H and 13C NMR spectroscopy were unable to

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L-Serine methyl ester hydrochloride