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792071

Spiro-MeOTAD

greener alternative

99% (HPLC)

Synonym(s):

N2,N2,N2′,N2′,N7,N7,N7′,N7′-octakis(4-methoxyphenyl)-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine, Spiro-OMeTAD, N2,N2,N2′,N2′,N7,N7,N7′,N7-octakis(4-methoxyphenyl)-9,9′-spirobi[9H-fluorene]-2,2′,7,7′-tetramine, Spiro-MeOTAD

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1 g
Please contact Customer Service for Availability
PLN 2,520.00
5 g
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PLN 9,740.00

About This Item

Empirical Formula (Hill Notation):
C81H68N4O8
CAS Number:
Molecular Weight:
1225.43
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:

PLN 2,520.00


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description

Hole Transport Layer

assay

99% (HPLC)

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

243-248 °C

λmax

306 nm in dichloromethane, 385 nm in dichloromethane

fluorescence

λem 429 nm in dichloromethane

greener alternative category

SMILES string

COC(C=C1)=CC=C1N(C2=CC=C(C=C2)OC)C(C=C3)=CC4=C3C(C=CC(N(C5=CC=C(C=C5)OC)C6=CC=C(C=C6)OC)=C7)=C7C84C9=C(C=CC(N(C%10=CC=C(C=C%10)OC)C%11=CC=C(C=C%11)OC)=C9)C%12=C8C=C(N(C%13=CC=C(C=C%13)OC)C%14=CC=C(C=C%14)OC)C=C%12

InChI

1S/C81H68N4O8/c1-86-65-29-9-53(10-30-65)82(54-11-31-66(87-2)32-12-54)61-25-45-73-74-46-26-62(83(55-13-33-67(88-3)34-14-55)56-15-35-68(89-4)36-16-56)50-78(74)81(77(73)49-61)79-51-63(84(57-17-37-69(90-5)38-18-57)58-19-39-70(91-6)40-20-58)27-47-75(79)76-48-28-64(52-80(76)81)85(59-21-41-71(92-7)42-22-59)60-23-43-72(93-8)44-24-60/h9-52H,1-8H3

InChI key

XDXWNHPWWKGTKO-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products,which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an enabling product used as a Hole Transport Material for high-performance solar cells and thus has been enhanced for energy efficiency. Click here for more information.

Application

High-mobility material used for white OLEDs to increase hole injection and transport. It is the best solid-state hole transporting material, to date, used to replace the liquid electrolyte for DSSC solar cells, due to an excellent pore-filling property in nanoporous TiO2 film with pore size of around 30-50 nm; attributed to its small molecular size.

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This Item
923230902500906018
assay

99% (HPLC)

assay

≥98.5% (HPLC)

assay

≥99.5%

assay

>98%

greener alternative category

, Enabling

greener alternative category

, Enabling

greener alternative category

Enabling,

greener alternative category

-

fluorescence

λem 429 nm in dichloromethane

fluorescence

-

fluorescence

-

fluorescence

-

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

-

description

Hole Transport Layer

description

Band gap 3.2 eV, Hole Transport Layer

description

-

description

-


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Articles

Dr Perini i profesor Correa-Baena omawiają najnowsze badania i wysiłki zmierzające do uzyskania wyższej wydajności i stabilności materiałów perowskitowych.

While dye sensitization as the basis for color photography has been accepted for a very long time,1 attempts to use this principle for the conversion of solar light to electricity generally had resulted only in very low photocurrents, below 100 nA/cm

Research focuses on sustainable and cost-effective power generation systems to meet the growing demand for environmentally friendly energy sources.

View All Articles

Related Content

Learn from leading experts about the evolution of PSCs, key material advancements, and innovative strategies to tackle current challenges.

Organic electronics utilizes organic conductors and semiconductors for applications in organic photovoltaics, organic light-emitting diodes, and organic field-effect transistors.

Elektronika organiczna wykorzystuje organiczne przewodniki i półprzewodniki do zastosowań w organicznej fotowoltaice, organicznych diodach elektroluminescencyjnych i organicznych tranzystorach polowych.


Lining He et al.
ACS applied materials & interfaces, 4(3), 1704-1708 (2012-03-07)
High-efficiency hybrid solar cells are fabricated using a simple approach of spin coating a transparent hole transporting organic small molecule, 2,2',7,7'-Tetrakis-(N,N-di-4-methoxyphenylamino)-9,9'-spirobifluorene (Spiro-OMeTAD) on silicon nanowires (SiNWs) arrays prepared by electroless chemical etching. The characteristics of the hybrid cells are investigated
Chemical compatibility between a hole conductor and organic dye enhances the photovoltaic performance of solid-state dye-sensitized solar cells
Young Soo Kwon,
Journal of Materials Chemistry, 22(17), 8641-8648 (2012)
Jun Jiang et al.
ChemSusChem, 13(2), 412-418 (2019-11-05)
Perovskite solar cells are sensitive to subtle changes in atmospheric conditions, resulting in problems such as the collapse of the perovskite structure and sharp drops in efficiency. Internal defects are also a big obstacle for high-quality polycrystalline perovskites. At present



Global Trade Item Number

SKUGTIN
792071-5G04061832950723
792071-1G04061835515646

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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