Merck
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904473

Sigma-Aldrich

4-Cyano-N-(trifluoromethoxy)pyridinium triflimide

≥95%

Synonym(s):
4-Cyano-1-(trifluoromethoxy)pyridin-1-ium bis((trifluoromethyl)sulfonyl)amide, Togni trifluoromethoxylation reagent
Empirical Formula (Hill Notation):
C9H4F9N3O5S2
CAS Number:
Molecular Weight:
469.26

Assay

≥95%

form

powder

storage temp.

2-8°C

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This Item
TMT00066
assay

≥95%

assay

-

form

powder

form

solid

storage temp.

2-8°C

storage temp.

-

Application

4-Cyano-N-(trifluoromethoxy)pyridinium triflimide is a bench-stable trifluoromethoxylation reagent developed in the Togni lab. Under irradiation with visible-light in the presence of a photocatalyst, N-O bond cleavage results in an OCF3 radical capable of arene C-H functionalization, providing trifluoromethoxy ethers.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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