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P9900

Sigma-Aldrich

Perfluorodecalin

95%

Synonym(s):
Octadecafluorodecahydronaphthalene (cis+trans), Perflunafene, Perfluorodecahydronaphthalene (cis+trans)
Empirical Formula (Hill Notation):
C10F18
CAS Number:
Molecular Weight:
462.08
Beilstein:
2067113
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

vapor density

17.5 (vs air)

Quality Level

assay

95%

refractive index

n20/D 1.3145 (lit.)

bp

142 °C (lit.)

mp

−10 °C (lit.)

density

1.908 g/mL at 25 °C (lit.)

SMILES string

FC1(F)C(F)(F)C(F)(F)C2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C2(F)C1(F)F

InChI

1S/C10F18/c11-1-2(12,5(17,18)9(25,26)7(21,22)3(1,13)14)6(19,20)10(27,28)8(23,24)4(1,15)16

InChI key

UWEYRJFJVCLAGH-UHFFFAOYSA-N

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Application

Perfluorodecalin is a fluorous solvent generally used as a primary component of the fluorous biphasic system (FBS) or the fluorous multiphasic system (FMS) in synthetic chemistry. It is also used as an additive to increase oxygen solubility in fermentation media.

Packaging

25 g in ampule

pictograms

Flame

signalword

Warning

hcodes

pcodes

Hazard Classifications

Flam. Liq. 3

Storage Class Code

3 - Flammable liquids

WGK Germany

WGK 3

Flash Point F

138.2 °F

Flash Point C

59 °C

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Dilution-free analysis from picoliter droplets by nano-electrospray ionization mass spectrometry.
Ryan T Kelly et al.
Angewandte Chemie (International ed. in English), 48(37), 6832-6835 (2009-08-19)
Helen G Pennington et al.
PLoS pathogens, 15(3), e1007620-e1007620 (2019-03-12)
The biotrophic fungal pathogen Blumeria graminis causes the powdery mildew disease of cereals and grasses. We present the first crystal structure of a B. graminis effector of pathogenicity (CSEP0064/BEC1054), demonstrating it has a ribonuclease (RNase)-like fold. This effector is part...
Palladium-Catalyzed Oxidation and Cyclization of Carbon-Carbon Triple Bonds in Fluorous Media Using Molecular Oxygen.
Wen Y, et al.
Synlett, 2011(07), 1023-1027 (2011)
Three-component one-pot synthesis of pyrimidinone derivatives in fluorous media: Ytterbium bis (perfluorooctanesulfonyl) imide complex catalyzed Biginelli-type reaction.
Hong M and Cai C
Journal of Heterocyclic Chemistry, 46(6), 1430-1432 (2009)
Convenient electrophilic fluorination of functionalized aryl and heteroaryl magnesium reagents.
Yamada S, et al.
Angewandte Chemie (International Edition in English), 122(12), 2261-2264 (2010)

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