If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
5.33002
Formic acid
98%-100%, for LC-MS LiChropur
Synonym(s):
Formic acid, Methanoic acid, Formylic acid
About This Item
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Product Name
Formic acid 98% - 100%, for LC-MS LiChropur™
Agency
suitable for DIN 38407-42
suitable for EPA 1633
suitable for ISO/CEN 15968-2010
Quality Level
reg. compliance
suitable for FDA C-010.02
vapor density
1.6 (vs air)
vapor pressure
44.8 mmHg ( 20 °C)
product line
LiChropur™
Assay
≥98% (acidimetric)
form
liquid
autoignition temp.
1004 °F
expl. lim.
12-38 % (v/v)
57 %
greener alternative product characteristics
Catalysis
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sustainability
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technique(s)
LC/MS: suitable
refractive index
n20/D 1.370 (lit.)
pH
2.2 (20 °C, 10 g/L in H2O)
bp
100-101 °C (lit.)
101 °C/1013 hPa
mp
8.2-8.4 °C (lit.)
transition temp
flash point 49.5 °C
solubility
water: soluble
density
1.22 g/mL at 25 °C (lit.)
cation traces
Al: ≤5.0 ppm
Ca: ≤10 ppm
Cu: ≤1.0 ppm
Fe: ≤5.0 ppm
K: ≤5.0 ppm
Mg: ≤2.0 ppm
NH4+: ≤10 ppm
Na: ≤5.0 ppm
application(s)
PFAS testing
greener alternative category
SMILES string
OC=O
storage temp.
15-25°C
InChI
1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChI key
BDAGIHXWWSANSR-UHFFFAOYSA-N
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1 of 4
This Item | 1.11670 | 1.00264 | PHR3559 |
|---|---|---|---|
| assay ≥98% (acidimetric) | assay ≥98% (acidimetric), 98-100% | assay ≥98% (alkalimetric) | assay - |
| agency suitable for DIN 38407-42, suitable for ISO/CEN 15968-2010, suitable for EPA 1633 | agency - | agency reag. Ph. Eur. | agency traceable to EP Y0001970, traceable to USP 1283200 |
| Quality Level 100 | Quality Level 100 | Quality Level 300 | Quality Level 300 |
| form liquid | form liquid | form liquid | form - |
| pH 2.2 (20 °C, 10 g/L in H2O) | pH 2.2 (20 °C, 10 g/L in H2O) | pH 2.2 (20 °C, 10 g/L in H2O) | pH - |
| storage temp. 15-25°C | storage temp. 2-30°C | storage temp. 15-25°C | storage temp. 2-8°C |
General description
Application
Legal Information
related product
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
121.1 °F - closed cup
Flash Point(C)
49.5 °C - closed cup
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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