Acetamiprid-N-desmethyl

Name: Acetamiprid-<I>N</I>-desmethyl
Brand: SIAL
Price: 1040 PLN

PESTANAL^®, analytical standard

Synonym(s):

N-(6-Chloro-3-pyridylmethyl)-N′-cyano-acetamidine

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10 MG

PLN 1,040.00

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About This Item

Empirical Formula (Hill Notation):

C₉H₉ClN₄

CAS Number:

190604-92-3

Molecular Weight:

208.65

MDL number:

MFCD08690484

UNSPSC Code:

41116107

PubChem Substance ID:

329754419

NACRES:

NA.24

Key Documents

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grade

analytical standard

Quality Level

100

product line

PESTANAL^®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

C\C(NCc1ccc(Cl)nc1)=N/C#N

InChI

1S/C9H9ClN4/c1-7(14-6-11)12-4-8-2-3-9(10)13-5-8/h2-3,5H,4H2,1H3,(H,12,14)

InChI key

AYEAUPRZTZWBBF-UHFFFAOYSA-N

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This Item	46417	33674	33887
Supelco 32979 Acetamiprid-N-desmethyl	Supelco 46417 Flumethrin	Supelco 33674 N-(6-Chloro-3-pyridylmethyl)-N-cyano-N-methylacetamidine	Supelco 33887 Desmethyl-formamido-pirimicarb
format neat	format neat	format neat	format neat
technique(s) HPLC: suitable, gas chromatography (GC): suitable	technique(s) HPLC: suitable, gas chromatography (GC): suitable	technique(s) HPLC: suitable, gas chromatography (GC): suitable	technique(s) HPLC: suitable, gas chromatography (GC): suitable
grade analytical standard	grade analytical standard	grade analytical standard	grade analytical standard
product line PESTANAL^®	product line PESTANAL^®	product line PESTANAL^®	product line PESTANAL^®
shelf life limited shelf life, expiry date on the label	shelf life limited shelf life, expiry date on the label	shelf life limited shelf life, expiry date on the label	shelf life limited shelf life, expiry date on the label
application(s) agriculture environmental	application(s) agriculture environmental	application(s) agriculture environmental	application(s) agriculture environmental

General description

Acetamiprid-N-desmethyl is a metabolite of the neonicotinoid insecticide, acetamiprid.[1]

Application

Acetamiprid-N-desmethyl may be used as a reference standard in the determination of acetamiprid-N-desmethyl in urine samples using ultra high-performance liquid chromatography coupled with orbitrap high resolution mass spectrometry (UHPLC-HRMS).[2]

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Acetamipride-Metabolite IM-2-1

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

GHS06

Signal Word

Danger

Hazard Statements

H301,H315,H319,H335

Precautionary Statements

P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Relationship between urinary N-desmethyl-acetamiprid and typical symptoms including neurological findings: a prevalence case-control study

Marfo TJ, et al.

PLoS ONE, 10(11), e0142172-e0142172 (2015)

Richard C Kolanczyk et al.

Xenobiotica; the fate of foreign compounds in biological systems, 50(7), 805-814 (2019-11-15)

Providing an alternative to pyrethroids, organophosphates, and carbamates, the neonicotinoids are now the most widely used insecticides in the world. They are water soluble and relatively stable in soil and water which allows for run-off through surface waters and thus

Development of Artificial Urine Certified Reference Material for Quantification of Neonicotinoid Insecticides.

Takamitsu Otake et al.

Journal of AOAC International, 103(6), 1469-1477 (2020-11-29)

Neonicotinoid insecticides (neonicotinoids) are widely used, however, they can negatively affect human health. Thus, neonicotinoids and their metabolites in human urine are analyzed globally to assess exposure levels and health risks. To properly assess the exposure levels and health risks

Determination of acetamiprid, imidacloprid, and spirotetramat and their relevant metabolites in pistachio using modified QuEChERS combined with liquid chromatography-tandem mass spectrometry.

Mohammad Faraji et al.

Food chemistry, 240, 634-641 (2017-09-28)

A QuEChERS based methodology was developed for the simultaneous identification and quantification of acetamiprid, imidacloprid, and spirotetramat and their relevant metabolites in pistachio by liquid chromatography-tandem mass spectrometry for the first time. First, sample extraction was done with MeCN:citrate buffer:NaHCO

Simultaneous determination of ten neonicotinoid insecticides and two metabolites in honey and Royal-jelly by solid-phase extraction and liquid chromatography-tandem mass spectrometry.

Jianbo Hou et al.

Food chemistry, 270, 204-213 (2018-09-04)

An analytical method based on liquid chromatography-tandem mass spectrometry (LC-MS/MS) method was developed for the first simultaneous determination of ten neonicotinoid insecticides (pymetrozine, dinotefuran, nitenpyram, thiamethoxam, flonicamid, imidacloprid, clothianidin, imidaclothiz, acetamiprid, thiacloprid) and two metabolites (4-trifluoromethylnicotinamide and N-desmethylacetamiprid) in honey

View All Related Papers

Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Neonicotinoids Ban: Impact on Plant Material

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.

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