Clothianidin-d₃

Name: Clothianidin-d<SUB>3</SUB>
Brand: SIAL
Price: 1040 PLN

PESTANAL^®, analytical standard

Synonym(s):

(E)-1-(2-Chloro-5-thiazolylmethyl)-3-(methyl-d₃)-2-nitroguanidine

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50 MG

PLN 1,040.00

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About This Item

Empirical Formula (Hill Notation):

C₆D₃H₅ClN₅O₂S

CAS Number:

1262776-24-8

Molecular Weight:

252.70

MDL number:

MFCD17019117

UNSPSC Code:

41116107

PubChem Substance ID:

329758241

NACRES:

NA.24

Key Documents

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grade

analytical standard

Quality Level

100

product line

PESTANAL^®

Assay

≥97.0% (HPLC)

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

mass shift

M+3

SMILES string

[2H]C([2H])([2H])N\C(NCc1cnc(Cl)s1)=N/[N+]([O-])=O

InChI

1S/C6H8ClN5O2S/c1-8-6(11-12(13)14)10-3-4-2-9-5(7)15-4/h2H,3H2,1H3,(H2,8,10,11)/i1D3

InChI key

PGOOBECODWQEAB-FIBGUPNXSA-N

Related Categories

Pesticide Standards

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1 of 4

This Item	68965	38176	39246
Supelco 56816 Clothianidin-d₃	Supelco 68965 Clothianidin	Supelco 38176 Thiamethoxam-d₃	Supelco 39246 Acetamiprid-d₃
format neat	format neat	format neat	format neat
technique(s) HPLC: suitable, gas chromatography (GC): suitable	technique(s) -	technique(s) HPLC: suitable, gas chromatography (GC): suitable	technique(s) HPLC: suitable, gas chromatography (GC): suitable
assay ≥97.0% (HPLC)	assay -	assay ≥98.0% (HPLC)	assay ≥98.0% (HPLC)
grade analytical standard	grade certified reference material, TraceCERT^®	grade analytical standard	grade analytical standard
product line PESTANAL^®	product line TraceCERT^®	product line PESTANAL^®	product line PESTANAL^®
shelf life limited shelf life, expiry date on the label	shelf life limited shelf life, expiry date on the label	shelf life limited shelf life, expiry date on the label	shelf life limited shelf life, expiry date on the label

General description

Find more information here: Neonicotinoids

Application

Clothianidin-d₃ may be used as a standard for the determination of neonicotinoid in milk by ultrahigh performance liquid chromatography coupled with tandem mass spectrometry (UHPLC-MS/MS).[1]

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H410

Precautionary Statements

P264 - P270 - P273 - P301 + P312 - P391 - P501

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Uptake and toxicity of clothianidin to monarch butterflies from milkweed consumption.

Timothy A Bargar et al.

PeerJ, 8, e8669-e8669 (2020-03-21)

Recent concern for the adverse effects from neonicotinoid insecticides has centered on risk for insect pollinators in general and bees specifically. However, natural resource managers are also concerned about the risk of neonicotinoids to conservation efforts for the monarch butterfly

Response of the mayfly (Cloeon dipterum) to chronic exposure to thiamethoxam in outdoor mesocosms.

Daniel B Pickford et al.

Environmental toxicology and chemistry, 37(4), 1040-1050 (2017-11-07)

Thiamethoxam is a widely used neonicotinoid insecticide that has been detected in surface water monitoring programs in North America and Europe. This has led to questions about its toxicity to nontarget insects, specifically those with an aquatic life stage. To

Development and Validation of an Ultra-Sensitive UHPLC-MS/MS Method for Neonicotinoid Analysis in Milk.

Lachat L and Glauser G

Journal of Agricultural and Food Chemistry, 66(32), 8639-8646 (2018)

High-Throughput Quantitation of Neonicotinoids in Lyophilized Surface Water by LC-APCI-MS/MS.

Lucas M Morrison et al.

Journal of AOAC International, 101(6), 1940-1947 (2018-05-23)

Background: Neonicotinoids are among the most widely used insecticides. Recently, there has been concern associated with unintended adverse effects on honeybees and aquatic invertebrates at low parts-per-trillion levels. Objective: There is a need for LC-MS/MS methods that are capable of

Field-scale examination of neonicotinoid insecticide persistence in soil as a result of seed treatment use in commercial maize (corn) fields in southwestern Ontario.

Arthur Schaafsma et al.

Environmental toxicology and chemistry, 35(2), 295-302 (2015-09-04)

Neonicotinoid insecticides, especially as seed treatments, have raised concerns about environmental loading and impacts on pollinators, biodiversity, and ecosystems. The authors measured concentrations of neonicotinoid residues in the top 5 cm of soil before planting of maize (corn) in 18 commercial

View All Related Papers

Protocols

Neonicotinoids

Learn more about Neonicotinoids - active substances used in plant protection products to control harmful insects.

Neonicotinoids Ban: Impact on Plant Material

Analysis of banned neonicotinoid insecticides from dandelion blossoms using QuEChERS and LC-MS.

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Clothianidin-d3

PESTANAL®, analytical standard