901755

nitro-Grela

≥95%, powder

• Synonym(s): (1,3-Dimesitylimidazolidin-2-ylidene)dichloro(2-isopropoxy-5-nitrobenzylidene)ruthenium(II)
• Empirical Formula (Hill Notation): C₃₁H₃₇Cl₂N₃O₃Ru
• CAS Number: 502964-52-5
• Molecular Weight: 671.62
• MDL number: MFCD28411645
• UNSPSC Code: 12161600
• NACRES: NA.22

Properties

• Product Name: nitro-Grela, ≥95%
• assay: ≥95%
• form: powder
• reaction suitability: core: ruthenium, reaction type: Olefin Metathesis, reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: >300 °C
• greener alternative category: Aligned
• storage temp.: 2-8°C
• SMILES string: [Ru+2](=C2N(CCN2c4c(cc(cc4C)C)C)c3c(cc(cc3C)C)C)=Cc1c(ccc(c1)[N+](=O)[O-])OC(C)C.[Cl-].[Cl-]
• InChI: 1S/C21H26N2.C10H11NO3.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-7(2)14-10-5-4-9(11(12)13)6-8(10)3;;;/h9-12H,7-8H2,1-6H3;3-7H,1-2H3;2*1H;/q;;;;+2/p-2
• InChI key: RQQSRSPQJIAORC-UHFFFAOYSA-L

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product features a novel catalyst design that enables challenging transformations under mild conditions, reducing energy consumption, waste, and solvent requirements while maintaining superior selectivity and yield. Click here for more information.

Application

nitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins.

Legal Information

Sold in collaboration with Apeiron Synthesis, Inc. Research quantities are 100 g / customer / year. For quantities that exceed the research limit, please contact the supplier at www.apeiron-synthesis.com.
PCT/EP2003/011222

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable