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Merck

06203

Sodium hydroxide

puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

Sodium hydroxide

Synonym(s):

‘Caustic soda’

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1 KG

PLN 190.00

5 KG

PLN 707.00

6 X 1 KG

PLN 1,340.00

PLN 190.00


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About This Item

Linear Formula:
NaOH
CAS Number:
Molecular Weight:
40.00
PubChem Substance ID:
UNSPSC Code:
12352302
NACRES:
NA.21
EC Number:
215-185-5
MDL number:
Assay:
98-100.5%
Vapor pressure:
<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

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Product Name

Sodium hydroxide, puriss., meets analytical specification of Ph. Eur., BP, NF, E524, 98-100.5%, pellets

SMILES string

[OH-].[Na+]
[OH-].[Na+]

InChI key

HEMHJVSKTPXQMS-UHFFFAOYSA-M

InChI

1S/Na.H2O/h;1H2/q+1;/p-1

vapor density

>1 (vs air)

vapor pressure

<18 mmHg ( 20 °C)
3 mmHg ( 37 °C)

grade

puriss.

assay

98-100.5%

form

pellets

quality

meets analytical specification of Ph. Eur., BP, NF, E524

impurities

≤0.0005% total nitrogen (N)
≤0.002% heavy metals (as Pb)
≤0.5% Na2CO3

mp

318 °C (lit.)

solubility

water: soluble 1260 g/L at 20 °C

density

2.13 g/cm3 at 20 °C

anion traces

chloride (Cl-): ≤20 mg/kg
phosphate (PO43-): ≤10 mg/kg
silicate (as SiO2): ≤100 mg/kg
sulfate (SO42-): ≤30 mg/kg

cation traces

Al: ≤10 mg/kg
As: ≤2 mg/kg
Ca: ≤10 mg/kg
Fe: ≤10 mg/kg
Hg: ≤1 mg/kg
K: ≤1000 mg/kg
Pb: ≤0.5 mg/kg

Quality Level

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1 of 4

This Item
65510430620-M306576
Quality Level

200

Quality Level

200

Quality Level

100

Quality Level

200

assay

98-100.5%

assay

97%

assay

≥98%

assay

99.99% trace metals basis

grade

puriss.

grade

-

grade

-

grade

-

solubility

water: soluble 1260 g/L at 20 °C

solubility

water: soluble 1260 g/L at 20 °C

solubility

water: soluble 1260 g/L at 20 °C

solubility

water: soluble 1,260 g/L at 20 °C

form

pellets

form

powder

form

pellets

form

pellets

vapor density

>1 (vs air)

vapor density

>1 (vs air)

vapor density

>1 (vs air)

vapor density

>1 (vs air)

Application

Sodium hydroxide can be used as:
  • A reagent in the gold-catalyzed selective oxidation of glycerol to glyceric acid.
  • A catalyst for the cross-dehydrogenative coupling of alcohols and hydrosilanes to synthesize silyl ethers.
  • A base in the transition-metal free Sonogashira-type couplings of aryl halides and alkynes to synthesize ynones in the presence of PEG as a phase-transfer agent.

General description

Sodium hydroxide, also known as lye and caustic soda, is a strong base used universally as a neutralization agent in the chemical industry, paper making, petroleum refining, cleaning compounds, and drain cleaners.

pictograms

Corrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable


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Chemoselective, solvent-free aldol condensation reaction.
Raston CL and Scott JL.
Green Chemistry, 2(2), 49-52 (2000)
M A Roberts et al.
Analytical chemistry, 69(11), 2035-2042 (1997-06-01)
This report describes a UV laser photoablation method for the production of miniaturized liquid-handling systems on polymer substrate chips. The fabrication of fluid channel and reservoir networks is accomplished by firing 200 mJ pulses from an UV excimer laser at
Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte: Part I. BH4- electro-oxidation on Au and Ag catalysts.
Chatenet M, et al.
Electrochimica Acta, 51(25), 5459-5467 (2006)
Silvio Carrettin et al.
Chemical communications (Cambridge, England), (7)(7), 696-697 (2002-07-18)
Glycerol is oxidised to glyceric acid with 100% selectivity using either 1% Au/charcoal or 1% Au/graphite catalyst under mild reaction conditions (60 degrees C, 3 h, water as solvent).
Determination of specific surface area of colloidal silica by titration with sodium hydroxide.
Sears Jr GW.
Analytical Chemistry, 28(12), 1981-1983 (1956)

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. What is the weight of one pellet?

    1 answer
    1. Unfortunately, no additional testing for the weight of one pellet is determined.

      Helpful?

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