Merck
All Photos(1)

195537

Sigma-Aldrich

tert-Butyl(chloro)diphenylsilane

98%

Synonym(s):
TBDPSCl, tert-Butyldiphenylchlorosilane
Linear Formula:
(CH3)3CSi(C6H5)2Cl
CAS Number:
Molecular Weight:
274.86
Beilstein:
644023
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

form

liquid

refractive index

n20/D 1.568 (lit.)

bp

90 °C/0.01 mmHg (lit.)

density

1.057 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)[Si](Cl)(c1ccccc1)c2ccccc2

InChI

1S/C16H19ClSi/c1-16(2,3)18(17,14-10-6-4-7-11-14)15-12-8-5-9-13-15/h4-13H,1-3H3

InChI key

MHYGQXWCZAYSLJ-UHFFFAOYSA-N

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Application

Silylating reagent used in the protection of alcohols and the preparation of silyl ethers.

Packaging

50, 250 g in Sure/Seal™
2, 10 g in glass bottle
1 kg in Sure/Seal™

Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

230.0 °F

Flash Point(C)

> 110 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

Polish Journal of Chemistry, 67, 685-685 (1993)
Tetrahedron Letters, 34, 3821-3821 (1993)
J A Robl et al.
Journal of medicinal chemistry, 34(9), 2804-2815 (1991-09-11)
A series of 2,3,4,(5),6-substituted pyridines containing a hydroxyphosphinyl functionally have been prepared and were evaluated for their ability to inhibit the enzyme HMG-CoA reductase. Systematic substitution of both R1-R4 and X-Y led to compounds of type 3-6 with in vitro
Maria Teresa Barros et al.
The Journal of organic chemistry, 69(22), 7772-7775 (2004-10-23)
1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.
Konstantina C Fylaktakidou et al.
ChemMedChem, 6(1), 153-168 (2010-11-26)
Polyphosphorylated and perphosphorylated hexopyranose monosaccharides and disaccharides were synthesized from parent or partially protected carbohydrates as potential allosteric effectors of hemoglobin. A study toward the construction of seven- and eight-membered cyclic pyrophosphates was also performed on the sugars which had

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