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480886

Sigma-Aldrich

Sodium borohydride

greener alternative

granular, 99.99% trace metals basis

Synonym(s):
Sodium tetrahydridoborate
Linear Formula:
NaBH4
CAS Number:
Molecular Weight:
37.83
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99.99% trace metals basis

form

granular

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

mp

>300 °C (dec.) (lit.)

greener alternative category

Enabling

SMILES string

[BH4-].[Na+]

InChI

1S/BH4.Na/h1H4;/q-1;+1

InChI key

YOQDYZUWIQVZSF-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Nanocrystalline superlattices in gold colloid solution have been prepared by ligand-induction using AuCl3 reduced with sodium borohydride. Nucleophilic addition of hydride ion from sodium borohydride is an inexpensive alternative method for the Baylis-Hillman reaction to form [E]-a-methylcinnamic acids. A reductant solution composed of NaBH4 and NaOH was used to form mercury cold vapor. NaBH4 may be used to generate hydrogen by catalytic hydrolysis.

Packaging

25, 100 g in poly bottle

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react. 1

Supplementary Hazards

Storage Class Code

4.3 - Hazardous materials, which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

156.2 °F

Flash Point(C)

69 °C

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Determination of Mercury in Fly Ash by Using Flow Injection Cold Vapor Isotope Dilution Inductively Coupled Plasma Mass Spectrometry.
Suh, Jung-Ki, et al.
Mass Spectrom., 3(2), 58-61 (2012)
Sandwich Enzyme--linked Immunosorbent Assay (ELISA) Analysis of Plant Cell Wall Glycan Connections.
Cornuault V and Knox JP
Bio-protocol, 4(8) (2014)
An effective nanosensor for organic molecules based on water-soluble mercaptopropionic acid-capped CdTe nanocrystals with potential application in high-throughput screening and high-resolution optical microscopy
Lau, Pick-Chung, et al.
Biomedical Optics Express, 5(7), 2420-2434 (2014)
Metal Borohydrides as Hydrogen Storage Materials
Soloveichik GL
Material Matters, 2(2), 11-11 (2007)
Toxicity of silver nanoparticles?nanoparticle or silver ion?
Beer C, et al.
Toxicology Letters, 208(3), 286-292 (2012)

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