75990

Sigma-Aldrich

Palladium on activated charcoal

greener alternative

10% Pd basis

Synonym(s):
Pd/C
Linear Formula:
Pd
MDL number:
eCl@ss:
38191001
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

10% Pd basis

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

greener alternative product characteristics

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Palladium on activated charcoal has been used for the reduction of trimesic acid to form a mixture of cis,cis and cis,trans isomers of 1,3,5-cyclohexanetricarboxylic acid. It can also be used for the conversion of benzylic and allylic alcohols into the corresponding carbonyl compounds in the presence of olefins as hydrogen acceptors.

Packaging

1, 10, 50 g in glass bottle

Other Notes

Catalyst for dehydrogenations

pictograms

Exclamation mark

signalword

Warning

hazcat

Eye Irrit. 2 - Skin Irrit. 2

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

Flash Point F

Not applicable

Flash Point C

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Brown, H. C.; Rangaishenvi, M. V.
Tetrahedron Letters, 31, 7115-7115 (1990)
Iida, H.; Watanabe, Y.; Kibayashi, C.
Journal of the American Chemical Society, 107, 5534-5534 (1985)
Orlek, B. S.; Wadsworth, H. et al.
Tetrahedron Letters, 32, 1241-1241 (1991)
Effenberger, F.; Muller, W.et al.
The Journal of Organic Chemistry, 55, 3064-3064 (1990)
Variable gelation time and stiffness of low-molecular-weight hydrogels through catalytic control over self-assembly.
Poolman JM, et al.
Nature Protocols, 9(4), 977-977 (2014)

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