Merck
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77292

Sigma-Aldrich

Pentafluoropropionic anhydride

purum, ≥97.0% (GC)

Synonym(s):
PFPA, Perfluoropropionic anhydride
Linear Formula:
(CF3CF2CO)2O
CAS Number:
Molecular Weight:
310.05
Beilstein:
1806446
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

grade

purum

assay

≥97.0% (GC)

form

liquid

bp

69-70 °C/735 mmHg (lit.)

density

1.571 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

InChI key

XETRHNFRKCNWAJ-UHFFFAOYSA-N

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Application

PFPA acylates amines, amino acids and other compounds. PFPA derivatives are highly volatile; used in GC separation
Pentafluoropropionic anhydride can be used to synthesize lithium 4,5-dicyano-2-(pentafluoroethyl)imidazole, a novel imidazole-derived salt with potential application as an electrolyte in lithium-ion batteries. It can also be used to prepare 1.3- bis(pentafluoropropionyl)azulene.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Precautionary Statements

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

Storage Class Code

8B - Non-combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

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Certificate of Origin

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