902810
4,4′-Bis(trifluoromethyl)-2,⋅2′-bipyridine
Synonym(s):
Photocatalysis ligand
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About This Item
Empirical Formula (Hill Notation):
C12H6F6N2
CAS Number:
Molecular Weight:
292.18
UNSPSC Code:
12352101
NACRES:
NA.22
MDL number:
Assay:
≥95%
Form:
solid
Pricing and availability is not currently available.
assay
≥95%
form
solid
reaction suitability
reagent type: catalyst, reagent type: ligand
reaction type: Photocatalysis
mp
78-80 °C
SMILES string
FC(F)(F)c1cc(ncc1)c2nccc(c2)C(F)(F)F
InChI
1S/C12H6F6N2/c13-11(14,15)7-1-3-19-9(5-7)10-6-8(2-4-20-10)12(16,17)18/h1-6H
InChI key
FFOMEQIMPYKURW-UHFFFAOYSA-N
Application
This ligand is used in Ir(III) complexes suitable for use in photocatalysis and phosphorescent OLEDs.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
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This Item | |||
|---|---|---|---|
| assay ≥95% | assay ≥95% | assay ≥95% | assay ≥95% |
| reaction suitability reagent type: catalyst, reagent type: ligand | reaction suitability - | reaction suitability reagent type: catalyst | reaction suitability - |
| form solid | form powder or crystals | form powder or crystals | form powder |
| mp 78-80 °C | mp 129-130 °C | mp 220-225 °C | mp - |
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Ryan M O'Donnell et al.
Journal of the American Chemical Society, 138(11), 3891-3903 (2016-02-24)
Excited state proton transfer studies of six Ru polypyridyl compounds with carboxylic acid/carboxylate group(s) revealed that some were photoacids and some were photobases. The compounds [Ru(II)(btfmb)2(LL)](2+), [Ru(II)(dtb)2(LL)](2+), and [Ru(II)(bpy)2(LL)](2+), where bpy is 2,2'-bipyridine, btfmb is 4,4'-(CF3)2-bpy, and dtb is 4,4'-((CH3)3C)2-bpy
Chip Le et al.
Science (New York, N.Y.), 360(6392), 1010-1014 (2018-06-02)
Transition metal-catalyzed arene functionalization has been widely used for molecular synthesis over the past century. In this arena, copper catalysis has long been considered a privileged platform due to the propensity of high-valent copper to undergo reductive elimination with a
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 902810-1G | 04061838695512 |