Merck
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1.09671

Supelco

1,4-Dioxane

for analysis EMSURE® ACS,ISO

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Synonym(s):
1,4-Dioxane, Glycolethylether, 1,4-Diethylene dioxide, 1,4-Dioxacyclohexane
Empirical Formula (Hill Notation):
C4H8O2
CAS Number:
Molecular Weight:
88.11
MDL number:
EC Index Number:
204-661-8

grade

ACS reagent

Quality Level

Agency

reag. ISO

vapor pressure

41 hPa ( 20 °C)

product line

EMSURE®

Assay

≥99.5% (GC)

form

liquid

autoignition temp.

300 °C

potency

5200 mg/kg LD50, oral (Rat)
7600 mg/kg LD50, skin (Rabbit)

expl. lim.

1.7-25.2 % (v/v)

impurities

≤0.0008 meq/g Acidity
≤0.005% Acetaldehyde
≤0.005% Peroxide (as H2O2)
≤0.01% Carbonyl compounds (as CO)
≤0.05% Formaldehyde
≤0.05% Water

evapn. residue

≤0.001%

color

APHA: ≤10

pH

6-8 (20 °C, 500 g/L in H2O)

bp

101.5 °C/1013 hPa

mp

12 °C

transition temp

flash point 11 °C

density

1.03 g/cm3 at 20 °C

cation traces

Al: ≤0.00005%
B: ≤0.000002%
Ba: ≤0.00001%
Ca: ≤0.00005%
Cd: ≤0.000005%
Co: ≤0.000002%
Cr: ≤0.000002%
Cu: ≤0.000002%
Fe: ≤0.00001%
Mg: ≤0.00001%
Mn: ≤0.000002%
Ni: ≤0.000002%
Pb: ≤0.00001%
Sn: ≤0.00001%
Zn: ≤0.00001%

storage temp.

2-30°C

InChI

1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2

Inchi Key

RYHBNJHYFVUHQT-UHFFFAOYSA-N

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1.03115PHR1549900640
1,4-Dioxane for analysis EMSURE® ACS,ISO

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1.09671

1,4-Dioxane

1,4-Dioxane EMPLURA®

Supelco

1.03115

1,4-Dioxane

1,4-Dioxane Pharmaceutical Secondary Standard; Certified Reference Material

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1,4-Dioxane anhydrous, ZerO2®, 99.8%

Sigma-Aldrich

900640

1,4-Dioxane

vapor pressure

41 hPa ( 20 °C)

vapor pressure

41 hPa ( 20 °C)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

vapor pressure

27 mmHg ( 20 °C), 40 mmHg ( 25 °C)

assay

≥99.5% (GC)

assay

≥99% (GC)

assay

-

assay

99.8%

form

liquid

form

liquid

form

-

form

liquid

autoignition temp.

300 °C

autoignition temp.

300 °C

autoignition temp.

356 °F

autoignition temp.

356 °F

expl. lim.

1.7-25.2 % (v/v)

expl. lim.

1.7-25.2 % (v/v)

expl. lim.

22 %

expl. lim.

22 %

General description

EMSURE grade solvents are suitable for a broad spectrum of classical lab applications, and are frequently used in regulated and highly demanding lab applications. EMSURE provides worldwide best and most extensive product specifications. We declare our EMSURE range to be in compliance with the ACS, with the reagent part of the European Pharmacopoeia (Reag. Ph Eur) and also with the ISO standards.

Analysis Note

Purity (GC): ≥ 99.5 %
Identity (IR): conforms
Color: ≤ 10 Hazen
Acidity: ≤ 0.0008 meq/g
Density (d 20 °C/ 4 °C): 1.030 - 1.035
Melting point: ≥ 11.0 °C
Formaldehyde: ≤ 0.05 %
Acetaldehyde: ≤ 0.005 %
Peroxide (as H₂O₂): ≤ 0.005 %
Carbonyl compounds (as CO): ≤ 0.01 %
Evaporation residue: ≤ 0.001 %
Water: ≤ 0.05 %
Al (Aluminium): ≤ 0.00005 %
B (Boron): ≤ 0.000002 %
Ba (Barium): ≤ 0.00001 %
Ca (Calcium): ≤ 0.00005 %
Cd (Cadmium): ≤ 0.000005 %
Co (Cobalt): ≤ 0.000002 %
Cr (Chromium): ≤ 0.000002 %
Cu (Copper): ≤ 0.000002 %
Fe (Iron): ≤ 0.00001 %
Mg (Magnesium): ≤ 0.00001 %
Mn (Manganese): ≤ 0.000002 %
Ni (Nickel): ≤ 0.000002 %
Pb (Lead): ≤ 0.00001 %
Sn (Tin): ≤ 0.00001 %
Zn (Zinc): ≤ 0.00001 %
Stabilized with 25 ppm 2,6-Di-tert-butyl-4-methylphenol (BHT).
ACS, ISO-reagent

Legal Information

EMSURE is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Danger

Hazard Statements

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

51.8 °F - closed cup

Flash Point(C)

11 °C - closed cup


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