Merck
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06300

Supelco

Aluminum oxide

activated, neutral, Brockmann Activity I

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Synonym(s):
Alumina
Linear Formula:
Al2O3
CAS Number:
1344-28-1
Molecular Weight:
101.96
EC Number:
215-691-6
MDL number:
MFCD00003424
eCl@ss:
38120402
PubChem Substance ID:
329748229
NACRES:
SB.52

grade

standard

form

powder

quality

activated, neutral

technique(s)

LPLC: suitable

matrix

Aluminum oxide

matrix active group

aluminum oxide

particle size

0.05-0.15 mm

pore size

60 Å mean pore size

surface area

155 m2/g

pH

7.0±0.5

mp

2040 °C (lit.)

separation technique

hydrophilic interaction (HILIC)

SMILES string

O=[Al]O[Al]=O

InChI

1S/2Al.3O

InChI key

TWNQGVIAIRXVLR-UHFFFAOYSA-N

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General description

Brockmann aluminum oxides are suitable for column chromatography and adsorptive filtration.
Aluminum oxides are generally used as solid support phases in solid phase extraction (SPE)-based clean-up procedures employed in chromatographic methods.

Application

Aluminum oxide has been used as a chromatographic column support for the purification of sn-2 monopalmitin prior to its determination by high performance liquid chromatography-evaporative light scattering detection (HPLC-ELSD).
It may be used for purification of fish tissue extract followed by liquid−liquid extraction into dichloromethane prior to the analysis for triarylmethane and phenothiazine dyes by liquid chromatography-tandem mass spectrometry (LC−MS/MS). It may also be used as a solid support phase for SPE-based analysis of pyrethroid insecticide residues in vegetable oils by gas chromatography-tandem mass spectrometry (GC-MS/MS).

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

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Multiresidue determination of triarylmethane and phenothiazine dyes in fish tissues by LC-MS/MS.
Tarbin JA, et al.
Analytica Chimica Acta, 625(2), 188-194 (2008)
Determination of pyrethroid insecticide residues in vegetable oils by using combined solid-phases extraction and tandem mass spectrometry detection.
Esteve-Turrillas FA, et al.
Analytica Chimica Acta, 553(1-2), 50-57 (2005)
A López-López et al.
Journal of chromatography. B, Biomedical sciences and applications, 760(1), 97-105 (2001-08-28)
An alternative method to determine the sn-2 monopalmitin in infant formulas was developed and validated. This method offers many advantages over the traditional methods. It follows the official method in the first steps, purification of the fat or oil through
Chien-Chih Lin et al.
Nanoscale, 5(17), 8090-8097 (2013-07-25)
We demonstrated a promising route for enhancing temperature sensitivity, improving saturation voltage, and reducing power consumption of the MOS(p) tunneling temperature sensors by introducing ultrathin Al2O3 into the dielectric stacks. Detailed illustrations of the working mechanism and device concept are
Jaakko Akola et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(25), 10129-10134 (2013-06-01)
Glass formation in the CaO-Al2O3 system represents an important phenomenon because it does not contain typical network-forming cations. We have produced structural models of CaO-Al2O3 glasses using combined density functional theory-reverse Monte Carlo simulations and obtained structures that reproduce experiments
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