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76778

Supelco

Methyl acrylate

analytical standard

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Linear Formula:
CH2=CHCOOCH3
CAS Number:
Molecular Weight:
86.09
Beilstein:
605396
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

vapor density

3 (vs air)

vapor pressure

67.5 mmHg ( 20 °C)

Assay

≥99.5% (GC)

autoignition temp.

874 °F

shelf life

limited shelf life, expiry date on the label

contains

~0.0015% hydroquinone monomethyl ether as stabilizer

expl. lim.

14.5 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.402 (lit.)
n20/D 1.403

bp

80 °C (lit.)

mp

−75 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

application(s)

environmental
petroleum

format

neat

SMILES string

COC(=O)C=C

InChI

1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3

InChI key

BAPJBEWLBFYGME-UHFFFAOYSA-N

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General description

This substance is listed on the positive list of the EU regulation 10/2011 for plastics intended to come into contact with food.

Application

Methyl acrylate can undergo transesterification reaction with 1-butanol under thermal conditions in the presence of hydrochloric acid to yield butyl acrylate as the major product.
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Pictograms

FlameSkull and crossbones

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

27.0 °F - closed cup

Flash Point(C)

-2.8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Organic Chemistry (2008)
Qiang Wang et al.
Journal of colloid and interface science, 375(1), 160-166 (2012-03-20)
The magnetic poly-(methyl acrylate-divinyl benzene) (MA-DVB) microspheres with micron size were synthesized by modified suspension polymerization method. Through stepwise reaction with methyl acrylate (MA) and ethylenediamine (EDA), the magnetic poly-(MA-DVB) microspheres with surface dendrimer containing amino groups were obtained. The
Shazia Abrar et al.
Analytical and bioanalytical chemistry, 400(8), 2577-2586 (2010-12-31)
Polyoxyethylene macromonomers are analyzed by one-dimensional liquid chromatography under different conditions, depending on the required information. These samples may contain polyethylene glycol (PEG) and the corresponding di(meth)acrylate besides the desired mono(meth)acrylate. The molar mass distribution (MMD) of the PEG and
Mustafa Ciftci et al.
Chemical communications (Cambridge, England), 48(82), 10252-10254 (2012-09-13)
Lightly branched, hyperbranched and cross-linked polymers with clickable sites were synthesized via a modified version of self-condensing photoinitiated copolymerization of methyl acrylate (MA) with propargyl acrylate (PA). The method is based on the use of a PA monomer containing two
Jens Voepel et al.
Biomacromolecules, 12(1), 253-259 (2010-12-21)
A multifunctional macroinitiator for single-electron-transfer mediated living radical polymerization (SET-LRP) was designed from acetylated galactoglucomannan (AcGGM) by α-bromoisobutyric acid functionalization of the anomeric hydroxyl groups on the heteropolysaccharide backbone. This macroinitiator, with a degree of substitution of 0.15, was used

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