Merck
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366374

Sigma-Aldrich

Zinc chloride solution

0.5 M in THF

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Linear Formula:
ZnCl2
CAS Number:
7646-85-7
Molecular Weight:
136.30
MDL number:
MFCD00011295
PubChem Substance ID:
329755428
NACRES:
NA.55

assay

470-600 mmol/L (silver nitrate titration)

form

liquid

concentration

0.5 M in THF

density

0.948 g/mL at 25 °C

SMILES string

Cl[Zn]Cl

InChI

1S/2ClH.Zn/h2*1H;/q;;+2/p-2

InChI key

JIAARYAFYJHUJI-UHFFFAOYSA-L

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General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Packaging

100, 800 mL in Sure/Seal™

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

Supplementary Hazards

EUH019

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

-4.0 °F - closed cup

Flash Point(C)

-20 °C - closed cup

Certificate of Analysis

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Certificate of Origin

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  1. Which document(s) contains shelf-life or expiration date information for a given product?

    If available for a given product, the recommended re-test date or the expiration date can be found on the Certificate of Analysis.

  2. How do I get lot-specific information or a Certificate of Analysis?

    The lot specific COA document can be found by entering the lot number above under the "Documents" section.

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  4. What is the Department of Transportation shipping information for this product?

    Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product. 

  5. Why does the MSDS for Product 366374 - 0.5M Zinc Chloride solution in THF state the prdouct may form explosive peroxides?

    Zinc Chloride is not a peroxide former itself but since its mixed with THF, THF is a peroxide former.

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    Ask a Scientist here.

Versatile palladium (II)-catalyzed Negishi coupling reactions with functionalized conjugated alkenyl chlorides.
Peyrat JF, et al.
Tetrahedron Letters, 44(35), 6703-6707 (2003)
Thin-layer electrochemistry of ferrocenylbenzene derivatives: Intramolecular electronic communication.
Wang MCP, et al.
Electrochimica Acta, 53(26), 7720-7725 (2008)
Zinc chloride-catalyzed chloromethylation of resins for solid phase peptide synthesis.
Feinberg RS and Merrifield RB.
Tetrahedron, 30(17), 3209-3212 (1974)
Molouk Beiromvand et al.
Preventive veterinary medicine, 109(1-2), 162-167 (2012-10-10)
Certain zoonotic parasites are enteropathogens in dogs that cause serious human disease such as cystic echinococcosis, human alveolar echinococcosis, visceral larva migrans, and ocular larva migrans. This study investigated the prevalence of intestinal parasites in dogs in the Chenaran County
Russell E Carter et al.
Journal of neurochemistry, 125(5), 673-684 (2013-03-19)
Spreading depolarization (SD) is a feed-forward wave that propagates slowly throughout brain tissue and recovery from SD involves substantial metabolic demand. Presynaptic Zn(2+) release and intracellular accumulation occurs with SD, and elevated intracellular Zn(2+) ([Zn(2+) ]i ) can impair cellular
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