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Network of Heterogeneous Catalyst Arrays on the Nitrogen-Doped Graphene for Synergistic Solar Energy Harvesting of Hydrogen from Water.
Shin, Sang Rim, et al.
Chemistry of Materials (2016)
Shuzhao Li et al.
Materials science & engineering. C, Materials for biological applications, 43, 350-358 (2014-09-02)
A water-soluble cationic diblock copolymer, CD-PAM-b-PMeDMA, was synthesized through atom transfer radical polymerization (ATRP) from a β-cyclodextrin (CD) macroinitiator with 10-active sites (10Br-β-CD). In order to reduce the cytotoxicity of the CD-PAM-b-PMeDMA, biocompatible polyacrylamide (PAM) was first introduced onto the...
Pan Dang et al.
Organic letters, 17(1), 34-37 (2014-12-17)
An efficient copper catalyzed strategy for the synthesis of a variety of benzothiazolethione derivatives has been developed. In the presence of CuCl, the three-component reaction of o-iodoanilines and K2S with p-toluenesulfonylmethyl isocyanide proceeded smoothly to obtain the corresponding benzothiazolethiones in...
Derak J James et al.
ACS applied materials & interfaces, 7(42), 23623-23632 (2015-10-20)
Derivatives of synthetic tetrahedrite, Cu12Sb4S13, are receiving increasing attention in the thermoelectric community due to their exploitation of plentiful, relatively nontoxic elements, combined with a thermoelectric performance that rivals that of PbTe-based compounds. However, traditional synthetic methods require weeks of...
B Ceken et al.
Bioorganicheskaia khimiia, 34(4), 546-557 (2008-08-13)
We investigated the reactions of substituted aryl radicals and aryl cations derived from arenediazonium ions and their ability to cause cleavage of supercoiled DNA and their tendency toward free radical or cation formation in the presence and absent of copper...
Shih-Chen Hsu et al.
Small (Weinheim an der Bergstrasse, Germany), 11(2), 195-201 (2014-08-15)
Au-Cu2 O core-shell nanocubes, octahedra, and rhombic dodecahedra display facet-dependent optical properties. Furthermore, different-sized Au-Cu2 O octahedra with 58, 65, 68, and 73 nm octahedral gold cores clearly show a transition from the shell thickness-independent gold surface plasmon resonance band...
Maximilian Knies et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(1), 127-132 (2017-10-05)
The reaction of Bi, BiCl
Milena E Miska et al.
Rapid communications in mass spectrometry : RCM, 29(24), 2341-2348 (2015-11-14)
The environmental occurrence of chlorinated acetic acids (CAAs) has been extensively studied, but the sources and transport are still not yet fully understood. A promising approach for source apportionment and process studies is the isotopic characterization of target compounds. We...
Erwan Gicquel et al.
Biomacromolecules, 20(7), 2545-2556 (2019-06-28)
This study investigates the adsorption of a block copolymer composed of a poly(2-(dimethylamino)ethyl methacrylate) (PDMAEMA) cationic polyelectrolyte and a poly(di(ethylene glycol) methyl ethermethacrylate) (PDEGMA) on oxidized cellulose nanocrystals (TO-CNCs) to produce hydrogels. PDMEAMA- b-PDEGMA was synthesized by atom-transfer radical polymerization....
Nicolas Visez et al.
Chemosphere, 73(1 Suppl), S90-S93 (2008-04-29)
Chlorination and thermal degradation of 2-chlorodibenzodioxin and dibenzofuran were investigated using sealed tubes at 350 degrees C in the presence of CuCl(2) or CuCl. Twelve organic species, including polychlorobenzenes, were identified and quantified as a function of residence time. Time...
Yin-Hua Shih et al.
Head & neck, 35(2), 250-256 (2012-03-01)
Lysyl oxidase (LOX) is a copper-dependent enzyme that cross-links collagen and elastin in the extracellular matrix. LOX overexpressed in various tumors. The manner in which LOX affects tumor growth remains controversial. Chemical treatment and gene transfection were used to induce...
Experimental study of copper (I) chloride complexing in hydrothermal solutions at 40 to 300 ?C and saturated water vapor pressure.
Xiao Z, et al.
Geochimica et Cosmochimica Acta, 62(17), 2949-2964 (1998)
Yunjiang Jiang et al.
ACS infectious diseases, 3(9), 676-687 (2017-08-02)
The prevalent wisdom on developing membrane active antimicrobials (MAAs) is to seek a delicate, yet unquantified, cationic-hydrophobic balance. Inspired by phages that use nanostructured protein devices to invade bacteria efficiently and selectively, we study here the antibiotic role of nanostructures...
Takayoshi Arai et al.
The Journal of organic chemistry, 73(13), 4903-4906 (2008-06-03)
A catalytic asymmetric Henry reaction has been developed with use of a sulfonyldiamine-CuCl complex as a catalyst. A series of new binaphthyl-containing sulfonyldiamine ligands (2a-h) were readily synthesized in two steps starting from commercially available chiral 1,2-diamines. The (R,R)-diamine-(R)-binaphthyl ligand...
Xiaoliang Xu et al.
Organic letters, 12(5), 897-899 (2010-02-04)
Promoted by CuCl/CCl(4), a variety of sulfonyl azides and tertiary amines were successfully coupled to give sulfonyl amidine derivatives in good to excellent yields. A possible mechanism for this reaction is discussed.
Solvothermal synthesis and mechanical characterization of single crystalline copper nanorings.
Zhan Y, et al.
Journal of Crystal Growth, 325(1), 76-80 (2011)
Bonil Koo et al.
Journal of the American Chemical Society, 131(9), 3134-3135 (2009-02-17)
The synthesis of monodisperse chalcopyrite (tetragonal) CuInSe(2) nanocrystals is reported. The nanocrystals have trigonal pyramidal shape, and they exhibited a common crystallographic orientation when drop-cast onto carbon substrates. A crystallographic model for the nanocrystals was developed. The nanocrystals are bounded...
Moglan Simona et al.
Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi, 116(3), 914-919 (2013-01-01)
Enalapril is an angiotensin-converting enzyme inhibitor widely used in the treatment of hypertension and heart failure. To design and validate a simple and sensitive spectrophotometric method. This method is based on a ternary complex formation between enalapril, copper (II), and...
Yew-Foon Tan et al.
Journal of proteome research, 11(7), 3860-3879 (2012-05-12)
Plant mitochondria are highly responsive organelles that vary their metabolism in response to a wide range of chemical and environmental conditions. Quantitative proteomics studies have begun to allow the analysis of these large-scale protein changes in mitochondria. However studies of...
Tatiana V Porto et al.
Dalton transactions (Cambridge, England : 2003), 44(46), 20176-20185 (2015-11-05)
The intricate interplay between polypeptide and metal ion binding underscores many of life's fundamental processes. Metalloregulators recognise and bind cognate metal ions during cellular metal stress, evoking a transcriptional response so as to maintain metal ion homeostasis. Members of the...
Chaoli Wang et al.
Journal of pharmaceutical and biomedical analysis, 102, 137-143 (2014-09-30)
The synthesis and performance of molecularly imprinted membranes (MIMs) as a solid phase extraction packing materials for the separation and purification of thymopentin from crude samples was described. In order to increase structural selectivity and imprinting efficiency, surface-initiated ATRP and...
Xiao Shen et al.
Nature communications, 5, 5431-5431 (2014-11-15)
The search for optimal thermoelectric materials aims for structures in which the crystalline order is disrupted to lower the thermal conductivity without degradation of the electron conductivity. Here we report the synthesis and characterisation of ternary nanoparticles (two cations and...
Copper (I) Chloride.
Bertz SH, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Marie S T Morin et al.
The Journal of organic chemistry, 77(4), 2013-2017 (2012-01-31)
A copper-catalyzed Petasis-type reaction of imines, acid chlorides, and organoboranes to form α-substituted amides is described. This reaction does not require the use of activated imines or the transfer of special units from the organoboranes and represent a useful generalization...
Sergiu Coseri et al.
Carbohydrate polymers, 90(4), 1415-1419 (2012-09-05)
NHPI (N-hydroxyphthalimide) was used to mediate the oxidation of cellulose fibers in the absence of sodium bromide, as traditionally was used in this kind of transformations, solely using sodium hypochlorite (NaOCl) as the primary oxidant. Avoiding the use of NaBr...
Yan Xiao et al.
International journal of oncology, 37(1), 81-87 (2010-06-02)
The metal ion copper is a cofactor essential for maintaining normal biological and physical functions in human beings. High copper levels have been found in variety of tumor tissues and are involved in tumor angiogenesis processes. The ubiquitin-proteasome system plays...
Qian Luo et al.
Chemical communications (Cambridge, England), (13)(13), 1593-1595 (2008-03-21)
Mediated by CuCl, 1,4-dilithio-1,3-dienes reacted with carbon monoxide (CO) to generate multi-substituted cyclopentadienones and/or their head-to-head dimers, via tandem CO insertion and intra/intermolecular cycloaddition of organocopper compounds.
Ganesan Bharathiraja et al.
Organic & biomolecular chemistry, 13(9), 2786-2792 (2015-01-22)
Various tetrasubstituted pyrroles/pyrazoles have been prepared from nitro-substituted 1,3-enynes with aromatic amines/hydrazines via a copper-catalyzed cascade aza-Michael addition, cyclization and aromatization at room temperature. This protocol is also effective for the synthesis of tetrasubstituted pyrazoles in high yields.
Yanjuan Liu et al.
Scientific reports, 5, 16879-16879 (2015-11-27)
Recently helical nanostructures such as nanosprings and nanocoils have drawn great interests in nanotechnology, due to their unique morphologies and physical properties, and they may be potential building blocks in sorts of electromechanical, magnetic, photoelectronic and plasmonic devices at micro/nanoscales....
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