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Growth of high-crystalline, single-layer hexagonal boron nitride on recyclable platinum foil.

Nano letters (2013-03-27)
Gwangwoo Kim, A-Rang Jang, Hu Young Jeong, Zonghoon Lee, Dae Joon Kang, Hyeon Suk Shin
ABSTRACT

Hexagonal boron nitride (h-BN) is gaining significant attention as a two-dimensional dielectric material, along with graphene and other such materials. Herein, we demonstrate the growth of highly crystalline, single-layer h-BN on Pt foil through a low-pressure chemical vapor deposition method that allowed h-BN to be grown over a wide area (8 × 25 mm(2)). An electrochemical bubbling-based method was used to transfer the grown h-BN layer from the Pt foil onto an arbitrary substrate. This allowed the Pt foil, which was not consumed during the process, to be recycled repeatedly. The UV-visible absorption spectrum of the single-layer h-BN suggested an optical band gap of 6.06 eV, while a high-resolution transmission electron microscopy image of the same showed the presence of distinct hexagonal arrays of B and N atoms, which were indicative of the highly crystalline nature and single-atom thickness of the h-BN layer. This method of growing single-layer h-BN over large areas was also compatible with use of a sapphire substrate.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Platinum, foil, thickness 0.025 mm, 99.9% trace metals basis
Platinum, foil, light tested, 25x25mm, thickness 0.05mm, as rolled, 99.95%
Platinum, foil, 6mm disks, thickness 0.125mm, as rolled, 99.95%
Platinum, foil, 25x25mm, thickness 0.125mm, as rolled, 99.95%
Platinum, foil, 10mm disks, thickness 0.025mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.0025mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.002mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.003mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.0075mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.0125mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.01mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99.95%
Platinum, foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99.99+%
Platinum, foil, 15x15mm, thickness 0.2mm, as rolled, 99.95%
Platinum, foil, 25x25mm, thickness 0.125mm, as rolled, 99.99+%
Platinum, foil, 25x25mm, thickness 0.1mm, as rolled, 99.95%
Platinum, foil, 25x25mm, thickness 0.1mm, as rolled, 99.99+%
Platinum, foil, 25x25mm, thickness 0.25mm, as rolled, 99.95%
Platinum, foil, 25x25mm, thickness 0.25mm, as rolled, 99.99+%
Platinum, foil, 25x25mm, thickness 0.25mm, as rolled, 99.999%
Platinum, foil, 30x30mm, thickness 0.2mm, as rolled, 99.95%
Platinum, foil, 50x50mm, thickness 0.125mm, as rolled, 99.95%
Platinum, foil, 50x50mm, thickness 0.125mm, as rolled, 99.99+%
Platinum, foil, 50x50mm, thickness 0.1mm, as rolled, 99.95%
Platinum, foil, 50x50mm, thickness 0.1mm, as rolled, 99.99+%
Platinum, foil, 0.05m coil, thickness 0.025mm, coil width .4mm, as rolled, 99.95%
Platinum, foil, 0.05m coil, thickness 0.025mm, coil width .85mm, as rolled, 99.95%
Platinum, foil, 0.05m coil, thickness 0.025mm, coil width 1.2mm, as rolled, 99.95%
Platinum, foil, 0.05m coil, thickness 0.025mm, coil width 1.6mm, as rolled, 99.95%
Platinum, foil, 0.05m coil, thickness 0.025mm, coil width 2mm, as rolled, 99.95%