178314

Sigma-Aldrich

N-Aminophthalimide

technical grade, 90%

Synonym(s):
N,N-Phthaloylhydrazine, unsym.
Empirical Formula (Hill Notation):
C8H6N2O2
CAS Number:
Molecular Weight:
162.15
Beilstein/REAXYS Number:
383756
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

grade

technical grade

Quality Level

assay

90%

mp

200-202 °C (lit.)

SMILES string

NN1C(=O)c2ccccc2C1=O

InChI

1S/C8H6N2O2/c9-10-7(11)5-3-1-2-4-6(5)8(10)12/h1-4H,9H2

InChI key

KSILMCDYDAKOJD-UHFFFAOYSA-N

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Application

N-Aminophthalimide was employed in the aziridination of chiral N-enoyl sultams. It was also used in the synthesis of n-phthalimidoaziridines.

Packaging

5 g in glass bottle
25 g in poly bottle

Other Notes

Remainder phthalhydrazide

Pictograms

Exclamation markHealth hazard

Signal Word

Danger

Target Organs

Respiratory system

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Kung-Shou Yang et al.
Organic letters, 4(7), 1107-1109 (2002-04-02)
[reaction: see text] Reaction of various N-enoyl oxazolidinones 5a-f with N-aminophthalimide and lead tetraacetate in the presence of camphor-derived chiral ligands provides the desired N-phthalimidoaziridines 6a-f in good to high enantiomeric excess (67-95% ee) at 0 degrees C within 15...
Journal of the Chemical Society. Chemical Communications, 1074-1074 (1993)

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