Merck
  • P26252
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P26252

Sigma-Aldrich

Phenylhydrazine

97%

Linear Formula:
C6H5NHNH2
CAS Number:
Molecular Weight:
108.14
Beilstein:
606080
EC Number:
MDL number:
PubChem Substance ID:
NACRES:
NA.22

vapor density

4.3 (vs air)

Quality Level

vapor pressure

<0.1 mmHg ( 20 °C)

Assay

97%

autoignition temp.

345 °F

refractive index

n20/D 1.607 (lit.)

bp

238-241 °C (lit.)

mp

18-21 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

SMILES string

NNc1ccccc1

InChI

1S/C6H8N2/c7-8-6-4-2-1-3-5-6/h1-5,8H,7H2

InChI key

HKOOXMFOFWEVGF-UHFFFAOYSA-N

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Phenylhydrazine 97%

Sigma-Aldrich

P26252

Phenylhydrazine

assay

97%

assay

97%

assay

≥99%

assay

≥95% (GC)

refractive index

n20/D 1.607 (lit.)

refractive index

n20/D 1.583 (lit.)

refractive index

-

refractive index

n20/D 1.493 (lit.)

bp

238-241 °C (lit.)

bp

54-55 °C/0.3 mmHg (lit.)

bp

-

bp

155-160 °C/32 mmHg (lit.)

mp

18-21 °C (lit.)

mp

-

mp

250-254 °C (dec.) (lit.)

mp

−70 °C (lit.)

density

1.098 g/mL at 25 °C (lit.)

density

1.038 g/mL at 25 °C (lit.)

density

-

density

1.123 g/mL at 25 °C (lit.)

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

100

Application

Phenylhydrazine can be used as a reactant in the synthesis of:
  • 4, 4′-(arylmethylene)-bis(3-methyl-1-phenyl-1H-pyrazol-5-ol)s by reacting with aryl aldehydes and acetoacetates in presence of N-bromo sulfonamide as a catalyst via one-pot pseudo-five-component condensation.
  • Thiazolidinones by treating with mercaptoacetic acid and aldehydes or ketones.
  • 5-[3,3,3-trifluoro-2-(phenylhydrazono)propyl]-1-phenyl-1H-pyrazole-3-carboxylic acid by reacting with 6-(trifluoromethyl)comanic acid.

It can be also used as a precursor for the preparation of selective carboxymethylated products at N-1 and N-2 by reacting with dimethyl carbonate (DMC) in the presence of a Bronsted base and metal salts as a catalyst.

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1

Storage Class Code

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

192.2 °F - closed cup

Flash Point(C)

89 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves


Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

EU REACH Annex XVII (Restriction List)

CAS No.

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

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