If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
240486
2-Methyl-2-butanol
≥99%, liquid, suitable for synthesis, ReagentPlus®
Synonym(s):
tert-Amyl alcohol, tert-Pentyl alcohol
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512,00 kr
1 160,00 kr
About This Item
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Product Name
2-Methyl-2-butanol, ReagentPlus®, ≥99%
InChI key
MSXVEPNJUHWQHW-UHFFFAOYSA-N
InChI
1S/C5H12O/c1-4-5(2,3)6/h6H,4H2,1-3H3
SMILES string
CCC(C)(C)O
vapor density
3 (vs air)
vapor pressure
12 mmHg ( 20 °C)
product line
ReagentPlus®
assay
≥99%
form
liquid
autoignition temp.
819 °F
expl. lim.
9 %
dilution
(for general lab use)
refractive index
n20/D 1.405 (lit.)
bp
102 °C (lit.)
mp
−12 °C (lit.)
density
0.805 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
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Related Categories
1 of 4
This Item | 721123 | 152463 | 19954 |
|---|---|---|---|
| assay ≥99% | assay ≥99% | assay 99% | assay ≥99.5% (GC) |
| Quality Level 100 | Quality Level 100 | Quality Level 200 | Quality Level 100 |
| form liquid | form liquid | form liquid | form - |
| expl. lim. 9 % | expl. lim. 9 % | expl. lim. 9 % | expl. lim. 9 % |
| mp −12 °C (lit.) | mp −12 °C (lit.) | mp −12 °C (lit.) | mp −12 °C (lit.) |
| autoignition temp. 819 °F | autoignition temp. 819 °F | autoignition temp. 819 °F | autoignition temp. 819 °F |
Application
- Palladium (II)-catalyzed ortho-C–H olefination of phenylacetic acids.[1]
- Rhodium-catalyzed direct C-H functionalization at the C7 position of N-pivaloylindoles.[2]
It may also be used in the preparation of 2-chloro-2-methylbutane by reacting with concentrated hydrochloric acid.[3]
General description
Legal Information
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
Storage Class
3 - Flammable liquids
wgk
WGK 1
flash_point_f
68.9 °F - closed cup
flash_point_c
20.5 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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