Merck
All Photos(1)

723932

Sigma-Aldrich

(2-Hydroxyphenyl)diphenylphosphine

97%

Synonym(s):
(2-Diphenylphosphino)phenol, (o-Diphenylphosphino)phenol, (o-Hydroxyphenol)diphenylphosphine
Empirical Formula (Hill Notation):
C18H15OP
CAS Number:
Molecular Weight:
278.28
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

142-150 °C

functional group

phosphine

SMILES string

Oc1ccccc1P(c2ccccc2)c3ccccc3

InChI

1S/C18H15OP/c19-17-13-7-8-14-18(17)20(15-9-3-1-4-10-15)16-11-5-2-6-12-16/h1-14,19H

InChI key

HGHOYIFINVBZKO-UHFFFAOYSA-N

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This Item
567728252972392960
assay

97%

assay

98%

assay

95%

assay

97%

form

solid

form

-

form

liquid

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

-

mp

142-150 °C

mp

105-110 °C (lit.)

mp

-

mp

82-84 °C (dec.) (lit.)

functional group

phosphine

functional group

phosphine

functional group

phosphine

functional group

phosphine

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

Application

Catalyst for:
  • Preparation of hydroxy(phosphinoxy)biphenyls
  • Formation of ethylene copolymers
  • Copolymerization of ethylene with linear olefins
  • Silylation of aryl halides

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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