266086

Sigma-Aldrich

powder, <425 μm, 99.5% trace metals basis

Empirical Formula (Hill Notation):
Cu
CAS号:
分子量:
63.55
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

质量水平

100

测定

99.5% trace metals basis

形式

powder

reaction suitability

core: copper
reagent type: catalyst

电阻率

1.673 μΩ-cm, 20°C

粒径

<425 μm

bp

2567 °C (lit.)

mp

1083.4 °C (lit.)

密度

8.94 g/mL at 25 °C (lit.)

SMILES string

[Cu]

InChI

1S/Cu

InChI key

RYGMFSIKBFXOCR-UHFFFAOYSA-N

包装

2 kg in glass bottle
25, 500 g in glass bottle

应用

用作环化和偶联反应的催化剂;例如,Ullmann偶联反应、环丙烷的制备、重氮酮或重氮酯的分解、C-O键的插入、末端炔烃和叠氮化物的[3+2]环加成反应和氢化反应。

象形图

FlameEnvironment

警示用语:

Danger

危险声明

hazcat

Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Sol. 1

storage_class_code

4.1B - Flammable solid hazardous materials

WGK Germany

WGK 3

闪点(F)

Not applicable

闪点(C)

Not applicable

个人防护装备

Eyeshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

分析证书

原产地证书 (CofO)

Seiko Ishida et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(48), 19507-19512 (2013-11-13)
Copper is an essential trace element, the imbalances of which are associated with various pathological conditions, including cancer, albeit via largely undefined molecular and cellular mechanisms. Here we provide evidence that levels of bioavailable copper modulate tumor growth. Chronic exposure...
R Squitti et al.
Neurology, 67(1), 76-82 (2006-07-13)
To assess whether serum copper in Alzheimer disease (AD) correlates with cognitive scores, beta-amyloid, and other CSF markers of neurodegeneration. The authors studied copper, ceruloplasmin, total peroxide, and antioxidants levels (TRAP) in serum; beta-amyloid in plasma; and copper, beta-amyloid, h-tau...
Stephen G Kaler et al.
The New England journal of medicine, 358(6), 605-614 (2008-02-08)
Menkes disease is a fatal neurodegenerative disorder of infancy caused by diverse mutations in a copper-transport gene, ATP7A. Early treatment with copper injections may prevent death and illness, but presymptomatic detection is hindered by the inadequate sensitivity and specificity of...
Daniel L Priebbenow et al.
Organic letters, 15(24), 6155-6157 (2013-11-28)
A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were...
Magnus Andersson et al.
Nature structural & molecular biology, 21(1), 43-48 (2013-12-10)
Heavy metals in cells are typically regulated by PIB-type ATPases. The first structure of the class, a Cu(+)-ATPase from Legionella pneumophila (LpCopA), outlined a copper transport pathway across the membrane, which was inferred to be occluded. Here we show by...

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