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Merck

441090

Sigma-Aldrich

2,2′-偶氮(2-甲基丙腈)

98%

别名:

α,α′-偶氮异丁腈, AIBN, VAZO 催化剂 64 自由基源, 偶氮二异丁腈, 自由基引发剂

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About This Item

线性分子式:
(CH3)2C(CN)N=NC(CH3)2CN
CAS号:
分子量:
164.21
Beilstein:
1708400
EC號碼:
MDL號碼:
分類程式碼代碼:
12162002
PubChem物質ID:
NACRES:
NA.23

品質等級

化驗

98%

形狀

powder

mp

102-104 °C (dec.) (lit.)

儲存溫度

2-8°C

SMILES 字串

CC(C)(\N=N\C(C)(C)C#N)C#N

InChI

1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3/b12-11+

InChI 密鑰

OZAIFHULBGXAKX-VAWYXSNFSA-N

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應用

2,2′-偶氮(2-甲基丙腈)可作为引发剂,用于:
  • 通过无皂乳液聚合作用制备聚苯乙烯。
  • 使用1-乙烯基咪唑制备分子印迹聚合物(MIP)。MIP可用于河流水样中酸性紫19染料的定量检测。

儲存和穩定性

警告:这些产品适用爆炸物法(Explosives Act),必须低温运输。将会加收额外运费。

象形圖

FlameExclamation mark

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Self-react. C

安全危害

儲存類別代碼

4.1A - Other explosive hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

122.0 °F

閃點(°C)

50 °C

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Tetrahedron Letters, 48, 5585-5585 (2007)
Miguel Luna Quinto et al.
Journal of hazardous materials, 384, 121374-121374 (2019-11-02)
A molecularly imprinted polymer (MIP) was developed for the determination of acid violet 19 (AV19) dye. The MIP was synthesized by polymerization using 1-vinyl imidazole (functional monomer) and 2,2'-azobis(2-methylpropionitrile) as the radical initiator. The functional monomer was previously selected by
Influence of the size of polystyrene synthesized through soap-free emulsion polymerization on antimicrobial activity
Tetsuya Yamamoto, et al.
Materials Today Communications, 20, 100572-100572 (2019)
Wenwen Li et al.
Macromolecular rapid communications, 32(1), 74-81 (2011-03-25)
Amphiphilic star shaped polymers with poly(ethylene oxide) (PEO) arms and cross-linked hydrophobic core were synthesized in water via either conventional free radical polymerization (FRP) or atom transfer radical polymerization (ATRP) techniques using a simple "arm-first" method. In FRP, PEO based
Lianghui Liu et al.
Organic letters, 14(22), 5692-5695 (2012-10-31)
In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to α-aminonitriles. These "metal-free" aerobic oxidative coupling reactions may find applications in a wide range of "green"

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