Merck

531480

Sigma-Aldrich

N-芴甲氧羰基-L-丙氨酸

95%

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别名:
N-芴甲氧羰基-L-丙氨酸, Fmoc-L-丙氨酸
Empirical Formula (Hill Notation):
C18H17NO4
CAS号:
分子量:
311.33
Beilstein:
2225975
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.26

质量水平

检测方案

95%

旋光性

[α]20/D −18°, c = 1 in DMF

reaction suitability

reaction type: C-H Activation
reaction type: Fmoc solid-phase peptide synthesis
reagent type: ligand
reaction type: Peptide Synthesis

mp

147-153 °C (lit.)

application(s)

peptide synthesis

官能团

Fmoc
amine
carboxylic acid

储存温度

2-8°C

SMILES string

C[C@H](NC(=O)OCC1c2ccccc2-c3ccccc13)C(O)=O

InChI

1S/C18H17NO4/c1-11(17(20)21)19-18(22)23-10-16-14-8-4-2-6-12(14)13-7-3-5-9-15(13)16/h2-9,11,16H,10H2,1H3,(H,19,22)(H,20,21)/t11-/m0/s1

InChI key

QWXZOFZKSQXPDC-NSHDSACASA-N

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3383384743647594
Fmoc-Phe-OH 98%

Sigma-Aldrich

338338

Fmoc-Phe-OH

Fmoc-N-Me-Ala-OH ≥97.0% (sum of enantiomers, HPLC)

Sigma-Aldrich

47594

Fmoc-N-Me-Ala-OH

optical activity

[α]20/D −18°, c = 1 in DMF

optical activity

[α]20/D −37°, c = 1 in DMF

optical activity

-

optical activity

[α]20/D −18.5±1°, c = 1% in DMF

mp

147-153 °C (lit.)

mp

180-187 °C (lit.)

mp

-

mp

-

functional group

Fmoc, amine, carboxylic acid

functional group

Fmoc, amine, carboxylic acid

functional group

Fmoc

functional group

Fmoc

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

reaction suitability

reaction type: C-H Activation

reaction suitability

reaction type: C-H Activation, reaction type: Fmoc solid-phase peptide synthesis, reagent type: ligand
reaction type: Peptide Synthesis

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

一般描述

Fmoc-Ala-OH又称为Fmoc-L-丙氨酸, 在Fmoc固相肽合成中起多种作用。

应用

Fmoc-Ala-OH的一般用途:
  • 作为制备三唑肽和氮杂肽的构件
  • 通过标准Fmoc固相肽合成法合成双阳离子卟啉肽
  • 不经过氮杂环丙烷化作用,将曼尼希加合物转化为α-卤化酰胺

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)


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