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Merck

723029

Sigma-Aldrich

氰甲基十二烷基 三硫代碳酸酯

98% (HPLC)

别名:

S-氰甲基-S-十二烷基三硫代碳酸酯

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About This Item

经验公式(希尔记法):
C15H27NS3
分子量:
317.58
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.23

化驗

98% (HPLC)

形狀

solid

儲存溫度

2-8°C

SMILES 字串

CCCCCCCCCCCCSC(=S)SCC#N

InChI

1S/C15H27NS3/c1-2-3-4-5-6-7-8-9-10-11-13-18-15(17)19-14-12-16/h2-11,13-14H2,1H3

InChI 密鑰

URUIKGRSOJEVQG-UHFFFAOYSA-N

一般說明

需要获取帮助以选择合适的 RAFT 试剂吗?请查阅 RAFT 试剂与单体相容性表格

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

>230.0 °F - closed cup

閃點(°C)

> 110 °C - closed cup


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

RAFT(可逆加成断裂链转移)聚合是一种可逆的去活化自由基聚合(RDRP),是给自由基聚合赋予活性的通用方法之一。

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

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实验方案

RAFT(可逆加成-断裂链转移)是一种活性自由基聚合反应,在有适合的连转移(RAFT)试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

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